Electrochemical methods for sustainable recovery of lithium from natural brines and battery recycling

被引:72
作者
Calvo, Ernesto Julio [1 ]
机构
[1] Univ Buenos Aires, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE CONICET, Fac Ciencias Exactas & Nat, Pabellon 2,Ciudad Univ,C1428EHA, Buenos Aires, DF, Argentina
关键词
Lithium; Brine; Recoverz; Electrodialusis; Mixing entropy; Battery recycling; SPINEL-TYPE LIMN2O4; PT/LAMBDA-MNO2; ELECTRODE; EXTRACTION; IONS; ELECTROINSERTION; CARBON; WATER;
D O I
10.1016/j.coelec.2019.04.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This short review covers the recent developments in electro-chemical methods for the extraction of lithium from natural brines, seawater, and battery recycling electrolytes by ion-pumping mixing entropy cells and electrodialysis. Lithium extraction by ion pumping takes advantage of the selective intercalation in lithium battery cathode materials and the concentration difference between the lithium source and the recovery electrolyte. Electrodialysis has attracted much interest in particular for large Mg/Li ratios in some natural brines.
引用
收藏
页码:102 / 108
页数:7
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