Electrochemical methods for sustainable recovery of lithium from natural brines and battery recycling

被引：70
作者：
Calvo, Ernesto Julio [1 ]
机构：
[1] Univ Buenos Aires, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE CONICET, Fac Ciencias Exactas & Nat, Pabellon 2,Ciudad Univ,C1428EHA, Buenos Aires, DF, Argentina
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2019年 / 15卷
关键词：
Lithium; Brine; Recoverz; Electrodialusis; Mixing entropy; Battery recycling; SPINEL-TYPE LIMN2O4; PT/LAMBDA-MNO2; ELECTRODE; EXTRACTION; IONS; ELECTROINSERTION; CARBON; WATER;
D O I：
10.1016/j.coelec.2019.04.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This short review covers the recent developments in electro-chemical methods for the extraction of lithium from natural brines, seawater, and battery recycling electrolytes by ion-pumping mixing entropy cells and electrodialysis. Lithium extraction by ion pumping takes advantage of the selective intercalation in lithium battery cathode materials and the concentration difference between the lithium source and the recovery electrolyte. Electrodialysis has attracted much interest in particular for large Mg/Li ratios in some natural brines.
引用
收藏
页码：102 / 108
页数：7
相关论文
共 55 条
  • [1] A First Assessment on the Scale-Up Possibilities of Different Electrochemical Techniques for Lithium Isotopic Enrichment
    Acosta, Lautaro N.
    Flexer, Victoria
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (33) : 11399 - 11413
  • [2] Evaporites and brines - geological, hydrological and chemical aspects of resource estimation
    Border, S.
    Sawyer, L.
    [J]. TRANSACTIONS OF THE INSTITUTIONS OF MINING AND METALLURGY SECTION B-APPLIED EARTH SCIENCE, 2014, 123 (02): : 95 - 106
  • [3] History of mercury use and environmental contamination at the Oak Ridge Y-12 Plant
    Brooks, Scott C.
    Southworth, George R.
    [J]. ENVIRONMENTAL POLLUTION, 2011, 159 (01) : 219 - 228
  • [4] Lithium recovery from salt lake brine by H2TiO3
    Chitrakar, Ramesh
    Makita, Yoji
    Ooi, Kenta
    Sonoda, Akinari
    [J]. DALTON TRANSACTIONS, 2014, 43 (23) : 8933 - 8939
  • [5] Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing
    Flexer, Victoria
    Fernando Baspineiro, Celso
    Ines Galli, Claudia
    [J]. SCIENCE OF THE TOTAL ENVIRONMENT, 2018, 639 : 1188 - 1204
  • [6] Lithium recovery by electrochemical transfer junction based on intercalation host matrix
    Guyot, E.
    Seghir, S.
    Diliberto, S.
    Lecuire, J. -M.
    Boulanger, C.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2012, 23 : 29 - 32
  • [7] Leaching Optimization of Battery Black Mass for Lithium Recovery by Electrochemical Junction Transfer (ETJ) Technology
    Guyot, Elodie
    Boulanger, Clotilde
    Lecuire, Jean-Marie
    [J]. 10TH ESEE: EUROPEAN SYMPOSIUM ON ELECTROCHEMICAL ENGINEERING, 2014, 41 : 67 - 72
  • [8] Modeling and Simulation of a Lithium Manganese Oxide/Activated Carbon Asymmetric Supercapacitor
    Hao, Chenglong
    Wang, Xiaofeng
    Yin, Yajiang
    You, Zheng
    [J]. JOURNAL OF ELECTRONIC MATERIALS, 2016, 45 (01) : 515 - 526
  • [9] New Insights into the Application of Lithium-Ion Battery Materials: Selective Extraction of Lithium from Brines via a Rocking-Chair Lithium-Ion Battery System
    He, Lihua
    Xu, Wenhua
    Song, Yunfeng
    Luo, Yunze
    Liu, Xuheng
    Zhao, Zhongwei
    [J]. GLOBAL CHALLENGES, 2018, 2 (02)
  • [10] Hoshino T, 2013, ECS T, V58, P173
123456