Iron-catalyzed synthesis of phenanthrenes via intramolecular hydroarylation of arene-alkynes

被引：2
|
作者：
Li, Yang [1 ]
Li, Yawei [1 ]
Hu, Xiao [1 ]
Pan, Guangxing [3 ]
Liu, Wangsheng [1 ]
Zhang, Yaopeng [2 ]
Guo, Hao [1 ,3 ]
机构：
[1] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China
[2] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[3] Fudan Univ, Acad Engn & Technol, Shanghai 220, Peoples R China
来源：
JOURNAL OF SAUDI CHEMICAL SOCIETY | 2019年 / 23卷 / 07期
基金：
对外科技合作项目（国际科技项目）;
关键词：
Hydroarylation; Cyclization; Phenanthrene; Iron catalysis; Lewis acid; IRON(II)-MEDIATED NITRENE TRANSFER; DERIVATIVES; ACTIVATION; SULFOXIDES; SULFIDES; BOCN(3);
D O I：
10.1016/j.jscs.2019.05.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An Fe(OTf)(3)-catalyzed intramolecular hydroarylation of arene-alkynes with high functional group tolerance has been reported, affording a series of phenanthrene derivatives efficiently. A low catalytic amount of Fe(OTf)(3) is applied in this reaction. This transformation provides a convenient and practical method for the preparation of phenanthrenes. (C) 2019 King Saud University. Production and hosting by Elsevier B.V.
引用
收藏
页码：967 / 972
页数：6
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