Recent advances in Pt-based electrocatalysts for PEMFCs

被引:70
作者
Zhang, Xuewei [1 ,2 ]
Li, Haiou [1 ,2 ]
Yang, Jian [1 ]
Lei, Yijie [1 ]
Wang, Cheng [1 ]
Wang, Jianlong [1 ]
Tang, Yaping [1 ]
Mao, Zongqiang [1 ]
机构
[1] Tsinghua Univ, Weichai Power Intelligent Mfg Joint Res Inst, INET, Beijing, Peoples R China
[2] Weichai Power Co Ltd, Weifang 261061, Shandong, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
OXYGEN-REDUCTION REACTION; NITROGEN-DOPED CARBON; PARTICLE-SIZE; CATALYTIC-ACTIVITY; HEAT-TREATMENT; ALLOY NANOPARTICLES; ORR ACTIVITY; OPERATING-CONDITIONS; PLATINUM NANOPARTICLES; LAYER DEPOSITION;
D O I
10.1039/d0ra05468b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to reduce the cost and improve the performance of proton exchange membrane fuel cells (PEMFCs), it is imperative to further enhance the activity and durability of Pt based electrocatalysts for the oxygen reduction reaction (ORR). This article analyzes the latest advances in Pt-based ORR electrocatalysts, including the Pt alloys, Pt-M core-shell structures, particle size effects, support effects, doping in Pt/PtM and post treatment. In addition, the performance of some of the developed novel electrocatalysts in membrane electrode assemblies (MEA) is also included for comparison, as they are rarely available and the superior activity and durability exhibited in RDE frequently doesn't translate into MEA.
引用
收藏
页码:13316 / 13328
页数:13
相关论文
共 133 条
[1]   Porous Platinum Nanotubes for Oxygen Reduction and Methanol Oxidation Reactions [J].
Alia, Shaun M. ;
Zhang, Gang ;
Kisailus, David ;
Li, Dongsheng ;
Gu, Shuang ;
Jensen, Kurt ;
Yan, Yushan .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (21) :3742-3746
[2]   Oxygen reduction activity of binary PtMn/C, ternary PtMnX/C (X = Fe, Co, Ni, Cu, Mo and, Sn) and quaternary PtMnCuX/C (X = Fe, Co, Ni, and Sn) and PtMnMoX/C (X = Fe, Co, Ni, Cu and Sn) alloy catalysts [J].
Ammam, Malika ;
Easton, E. Bradley .
JOURNAL OF POWER SOURCES, 2013, 236 :311-320
[3]   Ternary PtPdCu Multicubes as a Highly Active and Durable Catalyst toward the Oxygen Reduction Reaction [J].
An, Hong Ming ;
Zhao, Zhi Liang ;
Wang, Qi ;
Zhang, Lian Ying ;
Gu, Meng ;
Li, Chang Ming .
CHEMELECTROCHEM, 2018, 5 (10) :1345-1349
[4]   Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis [J].
Bu, Lingzheng ;
Zhang, Nan ;
Guo, Shaojun ;
Zhang, Xu ;
Li, Jing ;
Yao, Jianlin ;
Wu, Tao ;
Lu, Gang ;
Ma, Jing-Yuan ;
Su, Dong ;
Huang, Xiaoqing .
SCIENCE, 2016, 354 (6318) :1410-1414
[5]   Tailoring the catalytic activity of electrodes with monolayer amounts of foreign metals [J].
Calle-Vallejo, Federico ;
Koper, Marc T. M. ;
Bandarenka, Aliaksandr S. .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (12) :5210-5230
[6]   Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications [J].
Chen, Jingyi ;
Lim, Byungkwon ;
Lee, Eric P. ;
Xia, Younan .
NANO TODAY, 2009, 4 (01) :81-95
[7]   Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets [J].
Chen, Wei-Fu ;
Sasaki, Kotaro ;
Ma, Chao ;
Frenkel, Anatoly I. ;
Marinkovic, Nebojsa ;
Muckerman, James T. ;
Zhu, Yimei ;
Adzic, Radoslav R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (25) :6131-6135
[8]   Au-doped PtCo/C catalyst preventing Co leaching for proton exchange membrane fuel cells [J].
Choi, Juhyuk ;
Cho, Jinwon ;
Roh, Chi-Woo ;
Kim, Beom-Sik ;
Choi, Min Suk ;
Jeong, Hojin ;
Ham, Hyung Chul ;
Lee, Hyunjoo .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 247 :142-149
[9]   Ultralow-loading platinum-cobalt fuel cell catalysts derived from imidazolate frameworks [J].
Chong, Lina ;
Wen, Jianguo ;
Kubal, Joseph ;
Sen, Fatih G. ;
Zou, Jianxin ;
Greeley, Jeffery ;
Chan, Maria ;
Barkholtz, Heather ;
Ding, Wenjiang ;
Liu, Di-Jia .
SCIENCE, 2018, 362 (6420) :1276-+
[10]   Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst [J].
Chung, Hoon T. ;
Cullen, David A. ;
Higgins, Drew ;
Sneed, Brian T. ;
Holby, Edward F. ;
More, Karren L. ;
Zelenay, Piotr .
SCIENCE, 2017, 357 (6350) :479-483