Synthesis, Characterization and Applications of Poly(sulfanilic acid)-Based Triblock Copolymer

被引:10
作者
Murugesan, A. [1 ]
Meenarathi, B. [1 ]
Palanikumar, S. [1 ]
Kannammal, L. [1 ]
Anbarasan, R. [1 ]
机构
[1] Kamaraj Coll Engn & Technol, Dept Polymer Technol, Virudunagar 626001, India
关键词
Amphiphilic copolymer; Characterizations; FTIR; Humidity sensor; Synthesis; RING-OPENING POLYMERIZATION; ELECTRICAL-PROPERTIES; MONTMORILLONITE CLAY; EPSILON-CAPROLACTONE; DRUG-RELEASE; TETRAHYDROFURAN; ACID; POLYANILINE; NANOTUBES; POLYMERS;
D O I
10.1002/adv.21522
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A triblock copolymer consists of sulfanilic acid, tetrahydrofuran and epsilon-caprolactone was synthesized and characterized by various analytical techniques such as Fourier transform Infrared spectroscopy, UV-vis spectroscopy, fluorescence spectroscopy, thermogravimetric analysis, differential scanning calorimetry, field emission scanning electron microscopy, gel permeation chromatography and conductivity measurements. The percent relative humidity (RH) of poly(sulfanilic acid) (PSA; P1), poly(sulfanilic acid)-g-poly(tetrahydrofuran) (PSA-g-PTHF; P2), and poly(caprolactone)-block-poly(sulfanlic acid)-g-poly(tetrahydrofuran)-block-poly(epsilon-caprolactone) (PCL-b-PSA-g-PTHF-b-PCL; P3) were tested at different temperatures. This study infers that the cationically charged polymers exhibited excellent percent RH.
引用
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页数:9
相关论文
共 35 条
[1]   Conducting-Polymer Nanotubes Improve Electrical Properties, Mechanical Adhesion, Neural Attachment, and Neurite Outgrowth of Neural Electrodes [J].
Abidian, Mohammad Reza ;
Corey, Joseph M. ;
Kipke, Daryl R. ;
Martin, David C. .
SMALL, 2010, 6 (03) :421-429
[2]   Conducting-polymer nanotubes for controlled drug release [J].
Abidian, MR ;
Kim, DH ;
Martin, DC .
ADVANCED MATERIALS, 2006, 18 (04) :405-+
[3]   Polymers in sensor applications [J].
Adhikari, B ;
Majumdar, S .
PROGRESS IN POLYMER SCIENCE, 2004, 29 (07) :699-766
[4]  
Anbarasan R., 1999, POLYM NEWS, V24, P391
[5]   CATIONIC RING-OPENING POLYMERIZATION OF TETRAHYDROFURAN WITH KEGGIN-TYPE HETEROPOLYCOMPOUNDS AS SOLID ACID CATALYSTS [J].
Aouissi, Ahmed ;
Al-Deyab, Salim Salem ;
Al-Shehri, Hassan .
CHINESE JOURNAL OF POLYMER SCIENCE, 2010, 28 (03) :305-310
[6]   The Cationic Ring-Opening Polymerization of Tetrahydrofuran with 12-Tungstophosphoric Acid [J].
Aouissi, Ahmed ;
Al-Deyab, Salem S. ;
Al-Shahri, Hassan .
MOLECULES, 2010, 15 (03) :1398-1407
[7]  
Balster A. E., 2010, FIBRE CHEM+, V42, P215
[8]  
Bureau S G, 2008, MACROMOLECULES, V41, P3782, DOI DOI 10.1021/ma800626q
[9]   A novel report on Eosin Y functionalized MWCNT as an initiator for ring opening polymerization of ε-caprolactone [J].
Chen, Hung-Hsia ;
Anbarasan, R. ;
Kuo, Long-Sheng ;
Chen, Ping-Hei .
MATERIALS CHEMISTRY AND PHYSICS, 2011, 126 (03) :584-590
[10]   Synthesis and characterizations of novel acid functionalized and fluorescent poly(ε-caprolactone) [J].
Chen, Hung-Hsia ;
Anbarasan, R. ;
Kuo, Long-Sheng ;
Chen, Ping-Hei .
JOURNAL OF MATERIALS SCIENCE, 2011, 46 (06) :1796-1805