Dinuclear Metal Complex-Mediated Formation of CO2-Based Polycarbonates

被引：29

作者：

Romain, Charles ^{[1
]}

Thevenon, Arnaud ^{[1
]}

Saini, Prabhjot K. ^{[1
]}

Williams, Charlotte K. ^{[1
]}

机构：

[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England

来源：

CARBON DIOXIDE AND ORGANOMETALLICS | 2016年 / 53卷

基金：

英国工程与自然科学研究理事会;

关键词：

Bimetallic; Carbon dioxide chemistry; Catalysis; Dinuclear catalysts; Homogeneous catalysis; Polycarbonates; Polymerisation; Polymerisation catalysis; ASYMMETRIC ALTERNATING COPOLYMERIZATION; DIOXIDE-EPOXIDE COPOLYMERIZATION; RING-OPENING POLYMERIZATION; DIIMINATE ZINC CATALYSTS; CARBON-DIOXIDE; PROPYLENE-OXIDE; CYCLOHEXENE OXIDE; POLY(PROPYLENE CARBONATE); CO2/EPOXIDE COPOLYMERIZATION; CO-POLYMERIZATION;

D O I：

10.1007/3418_2015_95

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes selected metal catalysts for the copolymerisation of epoxides and carbon dioxide to produce polycarbonates. It highlights kinetic and mechanistic studies which have implicated di-or (multi-) metallic pathways for this catalysis and the subsequent development of highly active and selective di-/(multi-) nuclear catalysts. The emphasis is on homogeneous di-/bimetallic catalysts.

引用

页码：101 / 141

页数：41

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