Dinuclear Metal Complex-Mediated Formation of CO2-Based Polycarbonates

被引：29

作者：

Romain, Charles ^{[1
]}

Thevenon, Arnaud ^{[1
]}

Saini, Prabhjot K. ^{[1
]}

Williams, Charlotte K. ^{[1
]}

机构：

[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England

来源：

CARBON DIOXIDE AND ORGANOMETALLICS | 2016年 / 53卷

基金：

英国工程与自然科学研究理事会;

关键词：

Bimetallic; Carbon dioxide chemistry; Catalysis; Dinuclear catalysts; Homogeneous catalysis; Polycarbonates; Polymerisation; Polymerisation catalysis; ASYMMETRIC ALTERNATING COPOLYMERIZATION; DIOXIDE-EPOXIDE COPOLYMERIZATION; RING-OPENING POLYMERIZATION; DIIMINATE ZINC CATALYSTS; CARBON-DIOXIDE; PROPYLENE-OXIDE; CYCLOHEXENE OXIDE; POLY(PROPYLENE CARBONATE); CO2/EPOXIDE COPOLYMERIZATION; CO-POLYMERIZATION;

D O I：

10.1007/3418_2015_95

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes selected metal catalysts for the copolymerisation of epoxides and carbon dioxide to produce polycarbonates. It highlights kinetic and mechanistic studies which have implicated di-or (multi-) metallic pathways for this catalysis and the subsequent development of highly active and selective di-/(multi-) nuclear catalysts. The emphasis is on homogeneous di-/bimetallic catalysts.

引用

页码：101 / 141

页数：41

共 179 条

[31] Toward the design of double metal cyanides for the copolymerization of CO2 and epoxides
Darensbourg, DJ
Adams, MJ
Yarbrough, JC
[J]. INORGANIC CHEMISTRY, 2001, 40 (26) : 6543 - +
[32] Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst
Darensbourg, DJ
Yarbrough, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) : 6335 - 6342
[33] CATALYTIC ACTIVITY OF ZINC(II) PHENOXIDES WHICH POSSESS READILY ACCESSIBLE COORDINATION SITES - COPOLYMERIZATION AND TERPOLYMERIZATION OF EPOXIDES AND CARBON-DIOXIDE
DARENSBOURG, DJ
HOLTCAMP, MW
[J]. MACROMOLECULES, 1995, 28 (22) : 7577 - 7579
[34] Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts:: Lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides
Darensbourg, DJ
Wildeson, JR
Yarbrough, JC
Reibenspies, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (50) : 12487 - 12496
[35] Catalysts for the reactions of epoxides and carbon dioxide
Darensbourg, DJ
Holtcamp, MW
[J]. COORDINATION CHEMISTRY REVIEWS, 1996, 153 : 155 - 174
[36] Synthesis and structures of (dialkylamino)ethylcyclopentadienyl derivatives of zinc
Darensbourg, DJ
Wildeson, JR
Yarbrough, JC
[J]. ORGANOMETALLICS, 2001, 20 (21) : 4413 - 4417
[37] Manganese(III) schiff base complexes: Chemistry relevant to the copolymerization of epoxides and carbon dioxide
Darensbourg, Donald J.
Frantz, Eric B.
[J]. INORGANIC CHEMISTRY, 2007, 46 (15) : 5967 - 5978
[38] Making plastics from carbon dioxide:: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2
Darensbourg, Donald J.
[J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2388 - 2410
[39] A concise review of computational studies of the carbon dioxide-epoxide copolymerization reactions
Darensbourg, Donald J.
Yeung, Andrew D.
[J]. POLYMER CHEMISTRY, 2014, 5 (13) : 3949 - 3962
[40] Sequestering CO2 for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes
Darensbourg, Donald J.
Chung, Wan-Chun
Wang, Kecheng
Zhou, Hong-Cai
[J]. ACS CATALYSIS, 2014, 4 (05): : 1511 - 1515

← 1 2 3 4 5 6 7 8 9 10 →