Dinuclear Metal Complex-Mediated Formation of CO2-Based Polycarbonates

被引：29
作者：
Romain, Charles [1 ]
Thevenon, Arnaud [1 ]
Saini, Prabhjot K. [1 ]
Williams, Charlotte K. [1 ]
机构：
[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England
来源：
CARBON DIOXIDE AND ORGANOMETALLICS | 2016年 / 53卷
基金：
英国工程与自然科学研究理事会;
关键词：
Bimetallic; Carbon dioxide chemistry; Catalysis; Dinuclear catalysts; Homogeneous catalysis; Polycarbonates; Polymerisation; Polymerisation catalysis; ASYMMETRIC ALTERNATING COPOLYMERIZATION; DIOXIDE-EPOXIDE COPOLYMERIZATION; RING-OPENING POLYMERIZATION; DIIMINATE ZINC CATALYSTS; CARBON-DIOXIDE; PROPYLENE-OXIDE; CYCLOHEXENE OXIDE; POLY(PROPYLENE CARBONATE); CO2/EPOXIDE COPOLYMERIZATION; CO-POLYMERIZATION;
D O I：
10.1007/3418_2015_95
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review describes selected metal catalysts for the copolymerisation of epoxides and carbon dioxide to produce polycarbonates. It highlights kinetic and mechanistic studies which have implicated di-or (multi-) metallic pathways for this catalysis and the subsequent development of highly active and selective di-/(multi-) nuclear catalysts. The emphasis is on homogeneous di-/bimetallic catalysts.
引用
收藏
页码：101 / 141
页数：41
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