DSC evaluation of extra virgin olive oil stability under accelerated oxidative test: effect of fatty acid composition and phenol contents

被引:17
作者
Cerretani, Lorenzo [2 ]
Bendini, Alessandra [3 ]
Rinaldi, Massimiliano [1 ]
Paciulli, Maria [1 ]
Vecchio, Stefano [4 ]
Chiavaro, Emma [1 ]
机构
[1] Univ Parma, Dipartimento Ingn Ind, I-43124 Parma, Italy
[2] Univ Bologna, Dipartimento Econ & Ingn Agr, I-47521 Cesena, FC, Italy
[3] Univ Bologna, Dipartimento Sci Alimenti, I-47521 Cesena, FC, Italy
[4] Dipartimento Sci Base & Applicate Ingn, I-00185 Rome, Italy
关键词
Cooling; Differential scanning calorimetry; Extra virgin olive oil; Fatty acids; Total phenols; DIFFERENTIAL SCANNING CALORIMETRY; THERMAL-PROPERTIES; VEGETABLE-OILS;
D O I
10.5650/jos.61.303
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Three extra virgin olive oils having different fatty acid compositions and total phenol contents were submitted to an accelerated storage test at 60 degrees C for up to 21 weeks. Their oxidative status, evaluated by peroxide values and total phenolic content, was related to differential scanning calorimetry cooling profiles and thermal properties. Changes in crystallization profiles were consistent starting from 12 weeks for the two oil samples (B and C) that had a higher content of linoleic acid and medium/low amounts of phenols, respectively, whereas they became detectable at the end of the test for the remaining oil (sample A). Decrease of crystallization enthalpy and shift of transition towards lower temperature were also evident at 4 weeks of storage for samples B and C, whereas the same changes in the transition profile were noticeable at 12 weeks for sample A. Differential scanning calorimetry appears to be suitable for the discrimination of oxidative status of extra virgin olive oils with widely different fatty acid composition.
引用
收藏
页码:303 / 309
页数:7
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