Site-Selective Carbene-Induced C-H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes

被引：42
|
作者：
Liao, Kuangbiao [1 ]
Liu, Wenbin [1 ]
Niemeyer, Zachary L. [2 ]
Ren, Zhi [1 ]
Bacsa, John [1 ]
Musaev, Djamaladdin G. [1 ,3 ]
Sigman, Mathew S. [2 ]
Davies, Huw M. L. [1 ]
机构：
[1] Emory Univ, Dept Chem, 1515 Dickey Dr, Atlanta, GA 30322 USA
[2] Univ Utah, Dept Chem, 315 South,1400 East, Salt Lake City, UT 84112 USA
[3] Emory Univ, Cherry L Emerson Ctr Sci Computat, 1521 Dickey Dr, Atlanta, GA 30322 USA
来源：
ACS CATALYSIS | 2018年 / 8卷 / 01期
基金：
美国国家科学基金会;
关键词：
site-selectivity; non-activated C-H bond; enantioselective C-H functionalization; donor/acceptor carbene; dirhodium tetracarboxylate; predictive modeling; ACTIVATION; AMINATION; BONDS; TOOLS;
D O I：
10.1021/acscatal.7b03421
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Three types of dirhodium tetrakis(triarylcyclopropanecarboxylate) complexes were generated and shown to adopt disparate high symmetry structures. These catalysts were evaluated in the intermolecular C-H functionalization of an array of terminally substituted n-alkanes and displayed various site-selectivity as a function of catalyst and substrate structure, which could be correlated through quantitative relationships.
引用
收藏
页码：678 / 682
页数：5
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