Chlorobis[2-(2-pyridyl)ethanol]copper(II) chloride

被引:12
作者
Hamamci, S
Yilmaz, VT [1 ]
Thöne, C
机构
[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Samsun, Turkey
[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词
D O I
10.1107/S1600536804000157
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The structure of the title complex, [CuCl(pyet)(2)]Cl [pyet is 2-(2-pyridyl)ethanol, C7H9NO], consists of a chloride anion and a [Cu(Cl)(pyet)(2)](+) cation. In the cation, the copper(II) ion possesses a square-pyramidal coordination geometry, with a chloro and two neutral pyet ligands. Each pyet ligand acts as an N,O-bidentate ligand and forms a six-membered chelate ring around the copper(II) ion. The H atoms of the hydroxy groups of the pyet ligands form strong hydrogen bonds with chloride ions, while the phenyl and ethylene H atoms of pyet are involved in weak interactions with both the chloro ligand and chloride ion.
引用
收藏
页码:M159 / M161
页数:3
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