Aster koraiensis as nontoxic corrosion inhibitor for mild steel in sulfuric acid

被引:114
作者
Prabakaran, Mayakrishnan [1 ]
Kim, Seung-Hyun [1 ]
Mugila, Nithiyanandham [2 ]
Hemapriya, Venkatesan [2 ]
Parameswari, Kandasamy [2 ]
Chitra, Subramanian [2 ]
Chung, Ill-Min [1 ]
机构
[1] Konkuk Univ, Coll Life & Environm Sci, Dept Appl Biosci, Seoul 05029, South Korea
[2] PSGR Krishnammal Coll Women, Dept Chem, Coimbatore 641004, Tamil Nadu, India
关键词
Corrosion; Mild steel; Aster koraiensis; Electrochemical examination; SEM-EDX; LOW-CARBON STEEL; THERMODYNAMIC CHARACTERIZATION; ADSORPTION PROCESSES; METAL DISSOLUTION; NATURAL-PRODUCTS; EXTRACTS; POLYACETYLENE; PROTECTION; MECHANISM; CHLORIDE;
D O I
10.1016/j.jiec.2017.03.052
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Inhibition efficiency of Aster koraiensis leaf extract toward corrosion of mild steel in 1 M H2SO4 solution was investigated using weight loss, electrochemical, FT-IR, SEM, and EDX methods The individual phenolic compounds present in A. koraiensis extract were identified. Maximum efficiency of 90.53% was achieved at 2000 ppm of the extract. The corrosion kinetic parameters determined from the polarization curves indicated that the extract acted as a mixed-type inhibitor. Adsorption of the inhibitor on the mild steel surface obeyed the Langmuir isotherm. SEM investigations confirmed the formation of inhibition layer unto the metal surface by compounds present in the extract. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:235 / 242
页数:8
相关论文
共 56 条
[1]  
Ahn D., 1998, Illustrated Book of Korean Medicinal Herbs
[2]   Effect of inhibition synergism of zinc chloride and 2-mercaptobenzoxzole on protective performance of an ecofriendly silane coating on mild steel [J].
Alinejad, Shima ;
Naderi, Reza ;
Mahdavian, Mohammad .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 48 :88-98
[3]   The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid - Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies [J].
Amin, Mohammed A. ;
El-Rehim, Sayed S. Abd ;
El-Sherbini, E. E. F. ;
Bayoumi, Rady S. .
ELECTROCHIMICA ACTA, 2007, 52 (11) :3588-3600
[4]  
[Anonymous], 2015, INT J ELECTROCHEM SC
[5]   EN, EIS and polarization studies to evaluate the inhibition effect of 3H-phenothiazin-3-one, 7-dimethylamin on mild steel corrosion in 1 M HCl solution [J].
Ashassi-Sorkhabi, H. ;
Seifzadeh, D. ;
Hosseini, M. G. .
CORROSION SCIENCE, 2008, 50 (12) :3363-3370
[6]   Synthesis and characterization of some nonionic surfactants as corrosion inhibitors for steel in 1.0 M HCl (Experimental and computational study) [J].
Bedair, M. A. ;
Soliman, S. A. ;
Metwally, M. S. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2016, 41 :10-22
[7]   Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in mild steel/2,5-bis(n-thienyl)-1,3,4-thiadiazoles/hydrochloric acid system [J].
Bentiss, F ;
Lebrini, M ;
Lagrenée, M .
CORROSION SCIENCE, 2005, 47 (12) :2915-2931
[8]   Experimental and theoretical studies of xanthan gum and its graft co-polymer as corrosion inhibitor for mild steel in 15% HCl [J].
Biswas, Amrita ;
Pal, Sagar ;
Udayabhanu, G. .
APPLIED SURFACE SCIENCE, 2015, 353 :173-183
[9]   Gymnasterkoreayne G, a new inhibitory polyacetylene against NFAT transcription factor from Gymnaster koraiensis [J].
Dat, NT ;
Cai, XF ;
Shen, Q ;
Lee, IS ;
Lee, EJ ;
Park, YK ;
Bae, K ;
Kim, YH .
CHEMICAL & PHARMACEUTICAL BULLETIN, 2005, 53 (09) :1194-1196
[10]   Gymnastone, a new benzofuran derivative from Gymnaster koraiensis [J].
Dat, NT ;
Van Kiem, P ;
Cai, XF ;
Shen, QH ;
Bae, K ;
Kim, YH .
ARCHIVES OF PHARMACAL RESEARCH, 2004, 27 (11) :1106-1108