Preparation and properties of waterborne dual curable monomers and cured hybrid polymers for ink-jet applications

被引：62
作者：
Chang, Chi-Jung [1 ]
Tzeng, Haun-Yung [1 ]
机构：
[1] Feng Chia Univ, Dept Chem Engn, Taichung 40724, Taiwan
来源：
POLYMER | 2006年 / 47卷 / 26期
关键词：
hybrid material; morphology; dual curable;
D O I：
10.1016/j.polymer.2006.10.012
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Linear and star-like waterborne UV/moisture curable monomers with surface activity were synthesized by introducing different amounts of trimethoxysilane and methacrylate units into the monomer chains. The surface morphology, transparency and thermal properties of the cured hybrid polymer were found to be determined by the monomer structure, solvent, the amount and arrangement of trimethoxysilane groups. The polymer-silica hybrid materials crosslinked with both UV curing and sol-gel reaction exhibited good thermal properties at elevated temperature. Due to the surface activity of monomers in aqueous medium, aggregates on the film made by water diluted monomers are larger than those prepared by solvent diluted monomers. Larger aggregates lead to lower transparency. Hybrid films made by star-like monomer had smaller silica aggregates than those prepared by the linear monomers. Star-like monomer exhibited excellent compatibility with water-based pigment dispersion and good ink-jet printing properties. It can be used to improve the properties of the ink-jet printed micropatterns. (c) 2006 Elsevier Ltd. All rights reserved.
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页码：8536 / 8547
页数：12
相关论文
共 26 条
[1]   POLYURETHANE IONOMERS - EFFECTS OF EMULSIFICATION ON PROPERTIES OF HEXAMETHYLENE DIISOCYANATE-BASED POLYETHER POLYURETHANE CATIONOMERS [J].
CHAN, WC ;
CHEN, SA .
POLYMER, 1988, 29 (11) :1995-2001
[2]   Improving mechanical properties and chemical resistance of ink-jet printer color filter by using diblock polymeric dispersants [J].
Chang, CJ ;
Chang, SJ ;
Shih, KC ;
Pan, FL .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (22) :3337-3353
[3]   Effect of compositions and surface treatment on the jetting stability and color uniformity of ink-jet printed color filter [J].
Chang, CJ ;
Chang, SJ ;
Wu, FM ;
Hsu, MW ;
Chiu, WWW ;
Chen, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2004, 43 (12) :8227-8233
[4]   Influence of UV-curable compositions and rib properties on ink-jet-type color filter performance [J].
Chang, CJ ;
Wu, FM ;
Chang, SJ ;
Hsu, MW .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2004, 43 (9A) :6280-6285
[5]   Effects of polymeric dispersants and surfactants on the dispersing stability and high-speed-jetting properties of aqueous-pigment-based ink-jet inks [J].
Chang, CJ ;
Chang, SJ ;
Tsou, S ;
Chen, SI ;
Wu, FM ;
Hsu, MW .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (16) :1909-1920
[6]   Synthesis and characterization of poly(methyl methacrylate)-silica hybrid optical thin films [J].
Chen, WC ;
Lee, SJ .
POLYMER JOURNAL, 2000, 32 (01) :67-72
[7]  
DANG TD, 1995, ACS SYM SER, V585, pCH21
[8]   Internal polarity of class I and class II type sol-gel hybrid materials using aromatic aminoketones as solvatochromic probes for adsorbed solvents and the silicatic cage [J].
El-Sayed, M ;
Seifert, A ;
Spange, S .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2005, 34 (01) :77-94
[9]   Preparation and characterization of epoxy composites filled with functionalized nanosilica particles obtained via sol-gel process [J].
Kang, S ;
Hong, SI ;
Choe, CR ;
Park, M ;
Rim, S ;
Kim, J .
POLYMER, 2001, 42 (03) :879-887
[10]  
Kim HD, 1998, J APPL POLYM SCI, V67, P2153, DOI 10.1002/(SICI)1097-4628(19980328)67:13<2153::AID-APP5>3.0.CO
123