Metal Complexes as Molecular Electrocatalysts for Water Oxidation: A Mini-Review

被引：3
作者：
Fengzhao [1 ]
Sun, Ting [1 ]
Xia, Ning [1 ]
机构：
[1] Anyang Normal Univ, Coll Chem & Chem Engn, Henan Prov Key Lab New Optoelect Funct Mat, Anyang 455000, Henan, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2018年 / 13卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Electrocatalysts; water oxidation; oxygen evolution; metal complexes; OXYGEN EVOLUTION REACTION; COPPER ELECTROCATALYST; NICKEL(II) COMPLEX; BRANCHED PEPTIDE; NEUTRAL PH; IN-SITU; CATALYST; COBALT; CU(II); BINDING;
D O I：
10.20964/2018.05.27
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Electrocatalysts for splitting water into oxygen have increasingly attracted attention recently. First-row transition metal complexes (e.g., Cu, Fe, Co and Ni) have great potential to electrochemically catalyze water oxidation for oxygen evolution because of their abundance and cheapness. In this review, these metal complexes as water oxidation electrocatalysts were summarized. Their catalytic properties including overpotential, stability, and turnover rate were discussed.
引用
收藏
页码：4601 / 4612
页数：12
相关论文
共 52 条
[1]   Splitting Water with Cobalt [J].
Artero, Vincent ;
Chavarot-Kerlidou, Murielle ;
Fontecave, Marc .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266
[2]  
Barnett SM, 2012, NAT CHEM, V4, P498, DOI [10.1038/NCHEM.1350, 10.1038/nchem.1350]
[3]  
Chai YM, 2016, INT J ELECTROCHEM SC, V11, P3050
[4]   Cobalt-Salen Complexes as Catalyst Precursors for Electrocatalytic Water Oxidation at Low Overpotential [J].
Chen, Haiyan ;
Sun, Zijun ;
Liu, Xiang ;
Han, Ali ;
Du, Pingwu .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (17) :8998-9004
[5]   Copper(II) Catalysis of Water Oxidation [J].
Chen, Zuofeng ;
Meyer, Thomas J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (02) :700-703
[6]  
Codola Z., 2015, NAT COMMUN, V10, P1
[7]  
Coggins M.K., 2014, ANGEW CHEM, V126, P12422
[8]   Electrocatalytic Water Oxidation by a Monomeric Amidate-Ligated Fe(III)-Aqua Complex [J].
Coggins, Michael K. ;
Zhang, Ming-Tian ;
Vannucci, Aaron K. ;
Dares, Christopher J. ;
Meyer, Thomas J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (15) :5531-5534
[9]   How a [CoIV-O]2+ Fragment Oxidizes Water: Involvement of a Biradicaloid [CoII-(•O•)]2+ Species in Forming the O-O Bond [J].
Crandell, Douglas W. ;
Ghosh, Soumya ;
Berlinguette, Curtis P. ;
Baik, Mu-Hyun .
CHEMSUSCHEM, 2015, 8 (05) :844-852
[10]   Electrocatalytic water oxidation by a molecular cobalt complex through a high valent cobalt oxo intermediate [J].
Das, Debasree ;
Pattanayak, Santanu ;
Singh, Kundan K. ;
Garai, Bikash ;
Sen Gupta, Sayam .
CHEMICAL COMMUNICATIONS, 2016, 52 (79) :11787-11790
123456