Chelation-controlled regioselection in palladium-catalyzed carbonyl allylation by 4-pentene-1,3-diol or its cyclic carbonate

被引：6

作者：

Masuyama, Y

Mochizuki, S

Kurusu, Y

机构：

[1] Department of Chemistry, Sophia University, Chiyoda-ku, Tokyo 102

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 06期

关键词：

D O I：

10.1080/00397919708003045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

With cat. PdCl2(PhCN)(2) and SnCl2, 4-pentene-1, 3-diol caused regioselective carbonyl allylation at 3-position in DMF to produce 2-substituted 3-vinyltetrahydrofurans and/or 1-substituted 2-vinylbutane-1,4-diols, and cyclic carbonate of 4-pentene-1,3-diol caused regioselective carbonyl allylation at terminal 5-position in THF to produce 1-substituted 3-hexene-1,6-diols.

引用

页码：1015 / 1021

页数：7