Fe K-Edge X-ray absorption near-edge spectroscopy (XANES) and X-ray diffraction (XRD) analyses of LiFePO4 and its base materials

被引：6
|
作者：
Latif, C. [1 ]
Negara, V. S., I [1 ]
Wongtepa, W. [2 ]
Thamatkeng, P. [2 ]
Zainuri, M. [1 ]
Pratapa, S. [1 ]
机构：
[1] Inst Technol Sepuluh Nopember ITS, Dept Phys, Surabaya, Indonesia
[2] SLRI, Nakhon Ratchasima, Thailand
来源：
3RD INTERNATIONAL SYMPOSIUM ON FRONTIER OF APPLIED PHYSICS (ISFAP 2017) | 2018年 / 985卷
关键词：
D O I：
10.1088/1742-6596/985/1/012021
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
XANES analysis has been performed with the aim of knowing the Fe oxidation state in a synthesized LiFePO4 and its base materials. XANES measurements were performed at SLRI on energy around Fe K-edge. An XRD analysis has also been performed with the aim of knowing the phase composition, lattice parameters and crystallite size of the LiFePO4 as well as the base materials. From the XRD analysis, it was found that the dominating phase in the iron sand sample was Fe3O4 and the only phase found after calcination was LiFePO4. The latter phase exhibited crystallite size of 100 nm and lattice parameters a = 10.169916 angstrom, b = 5.919674 angstrom, c = 4.627893 angstrom. Qualitative analysis of XANES data revealed that the oxidation number of Fe in the sample before calcination was greater than that after calcination and Fe in the natural iron sand, indicated by the E0 values of 7129.2 eV, 7120.6 eV and 7124.4 eV respectively.
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页数：5
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