Facile sol-gel derived nanostructured spinel Co3O4 as electrode material for high-performance supercapattery and lithium-ion storage

被引:57
作者
Devi, Vaithiyanathan Sankar [1 ]
Athika, Mattath [1 ]
Duraisamy, Ezhumalai [1 ]
Prasath, Arul [1 ]
Sharma, Arumugam Selva [1 ]
Elumalai, Perumal [1 ]
机构
[1] Pondicherry Univ, Madanjeet Sch Green Energy Technol, Dept Green Energy Technol, Pondicherry 605014, India
关键词
Supercapattery; Lithium-ion battery; Anodes: cobalt oxide; Sol-gel; Energy density; ANODE MATERIALS; NI FOAM; MORPHOLOGY; BATTERY; NANOSHEETS; CAPACITY;
D O I
10.1016/j.est.2019.100815
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This work reports high-performance supercapattery and lithium-ion storage using nanostructured spinel cobalt oxide (Co3O4) generated by modified facile sol-gel process. The formation of spinel Co3O4 was confirmed by materials characterization techniques. Electrochemical studies of the Co3O4 in KOH revealed excellent redox features. The supercapattery device in the form of CR-2032 coin cell consisting of the Co3O4 as positive electrode and reduced graphene-oxide as negative electrode delivered high energy density of 40 Wh kg(-1) at power density of 742 W kg(-1). In addition, the half-cell in the form of CR-2032 coin cell having the Co3O4 as anode and lithium metal as counter electrode exhibited stabilized lithium storage capacity of 620 mA h g(-1) with high Coloumbic efficiency. Glowing of a commercial LED for more than 15 min using the fabricated supercapattery was demonstrated. The nanofeatures of the sol-gel derived Co3O4 led to such excellent charge storage and lithium storage performances.
引用
收藏
页数:8
相关论文
共 26 条
[1]   Electrochemical response of a high-power asymmetric supercapacitor based on tailored MnOx/Ni foam and carbon cloth in neutral and alkaline electrolytes [J].
Aldama, I ;
Siwek, K., I ;
Amarilla, J. M. ;
Rojo, J. M. ;
Eugenio, S. ;
Siva, T. M. ;
Montemor, M. F. .
JOURNAL OF ENERGY STORAGE, 2019, 22 :345-353
[2]   Ordered mesoporous Co3O4/CMC nanoflakes for superior cyclic life and ultra high energy density supercapacitor [J].
Babu, I. Manohara ;
William, J. Johnson ;
Muralidharan, G. .
APPLIED SURFACE SCIENCE, 2019, 480 :371-383
[3]   Construction of Co3O4 nanotubes as high-performance anode material for lithium ion batteries [J].
Chen, Minghua ;
Xia, Xinhui ;
Yin, Jinghua ;
Chen, Qingguo .
ELECTROCHIMICA ACTA, 2015, 160 :15-21
[4]   [Co(salen)] derived Co/Co3O4 nanoparticle@carbon matrix as high-performance electrode for energy storage applications [J].
Duraisamy, E. ;
Gurunathan, P. ;
Das, Himadri T. ;
Ramesha, K. ;
Elumalai, P. .
JOURNAL OF POWER SOURCES, 2017, 344 :103-110
[5]   Facile scalable synthesis of Co3O4/carbon nanotube hybrids as superior anode materials for lithium-ion batteries [J].
Fang, Zhiguo ;
Xu, Weiwei ;
Huang, Tao ;
Li, Maolin ;
Wang, Wanren ;
Liu, Yanping ;
Mao, Chaochao ;
Meng, Fanli ;
Wang, Mengjiao ;
Cheng, Minghai ;
Yu, Aishui ;
Guo, Xiaohui .
MATERIALS RESEARCH BULLETIN, 2013, 48 (10) :4419-4423
[6]   Oriented synthesis of Co3O4 core-shell microspheres for high-performance asymmetric supercapacitor [J].
Guo, Dongxuan ;
Song, Xiumei ;
Li, Fengbo ;
Tan, Lichao ;
Ma, Huiyuan ;
Zhang, Lulu ;
Zhao, Yuanqing .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 546 :1-8
[7]   Sol-gel synthesis of mesoporous Co3O4 octahedra toward high-performance anodes for lithium-ion batteries [J].
Guo, Jinxue ;
Chen, Lei ;
Zhang, Xiao ;
Jiang, Bin ;
Ma, Linzheng .
ELECTROCHIMICA ACTA, 2014, 129 :410-415
[8]   A Convenient Synthesis Route for Co3O4 Hollow Microspheres and Their Application as a High Performing Anode in Li-Ion Batteries [J].
Gurunathan, Padalingam ;
Ette, Pedda Masthanaiah ;
Lakshminarasimhan, Narayanan ;
Ramesha, Kannadka .
ACS OMEGA, 2017, 2 (11) :7647-7657
[9]   Micro-/Nanostructured Co3O4 Anode with Enhanced Rate Capability for Lithium-Ion Batteries [J].
Huang, Guoyong ;
Xu, Shengming ;
Lu, Shasha ;
Li, Linyan ;
Sun, Hongyu .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) :7236-7243
[10]   Facile synthesis of hierarchical Co3O4@MnO2 core-shell arrays on Ni foam for asymmetric supercapacitors [J].
Huang, Ming ;
Zhang, Yuxin ;
Li, Fei ;
Zhang, Lili ;
Wen, Zhiyu ;
Liu, Qing .
JOURNAL OF POWER SOURCES, 2014, 252 :98-106