Are Ionic Liquids Chemically Stable?

被引：534

作者：

Wang, Binshen ^{[1
]}

Qin, Li ^{[1
]}

Mu, Tiancheng ^{[2
]}

Xue, Zhimin ^{[3
]}

Gao, Guohua ^{[1
]}

机构：

[1] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Dept Chem, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China

[2] Renmin Univ China, Dept Chem, 59 Zhongguancun St, Beijing 100872, Peoples R China

[3] Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing Key Lab Lignocellulos Chem, 35 Tsinghua East Rd, Beijing 100083, Peoples R China

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 10期

基金：

中国国家自然科学基金;

关键词：

HETEROCYCLIC CARBENE COMPLEXES; THERMAL-STABILITY; CARBON-DIOXIDE; IMIDAZOLIUM CATIONS; ALKALINE STABILITY; LIGNOCELLULOSIC BIOMASS; HYDROGEN CARBONATE; ATOM-EFFICIENT; ROCKET FUELS; CO2;

D O I：

10.1021/acs.chemrev.6b00594

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids have attracted a great deal of interest in recent years, illustrated by their applications in a variety of areas involved with chemistry, physics, biology, and engineering. Usually, the stabilities of ionic liquids are highlighted as one of their outstanding advantages. However, are ionic liquids really stable in all cases? This review covers the chemical stabilities of ionic liquids. It focuses on the reactivity of the most popular imidazolium ionic liquids at structural positions, including C2 position, N1 and N3 positions, and C4 and C5 positions, and decomposition on the imidazolium ring. Additionally, we discuss decomposition of quaternary ammonium and phosphonium ionic liquids and hydrolysis and nucleophilic reactions of anions of ionic liquids. The review aims to arouse caution on potential decomposition of ionic liquids and provides a guide for better utilization of ionic liquids.

引用

页码：7113 / 7131

页数：19

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