Glass forming ability, non-isothermal crystallization kinetics, and mechanical property of Zr61.5Al10.7Cu13.65Ni14.15 metallic glass

被引:35
作者
Cai, A. H. [1 ,2 ]
An, W. K. [1 ]
Luo, Y. [1 ]
Li, T. L. [1 ]
Li, X. S. [1 ]
Xiong, X. [2 ]
Liu, Y. [2 ]
机构
[1] Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414000, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
关键词
Glass forming ability; Thermal stability; Non-isothermal crystallization; Mechanical property; SOFT-MAGNETIC PROPERTIES; SUPERCOOLED LIQUID; TRANSITION; DEFORMATION; FRAGILITY; CU; RELAXATIONS; TEMPERATURE; BEHAVIOR;
D O I
10.1016/j.jallcom.2009.10.125
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The glass forming ability (GFA), thermal stability, non-isothermal crystallization kinetics, and mechanical property of Zr61.5Al10.7Cu13.65Ni14.15 glass forming alloy were investigated. Its maximum glass forming dimension reaches up to 5.5 mm and its critical cooling rate is less than 40 K s(-1). The apparent activation energies for glass transition Eg, onset crystallization Ex, and crystallization peak E-p are 214.56 +/- 16.14, 267.42 +/- 9.36, and 305.69 +/- 7.31 kJ mol(-1), respectively. Small fragility parameter m about 17 indicates its better thermodynamic stability and GFA. In addition, its elastic strain limit, compressive strength, and Young's modulus are 2.73%, 1.81 GPa, and 70.47 GPa, respectively. Its V-shape fracture mode is different form other bulk metallic glasses. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:642 / 646
页数:5
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