Sensitized near-infrared lanthanide luminescence from Nd(III)- and Yb(III)-based cyclen-ruthenium coordination conjugates

被引：89
作者：
Senechal-David, Katell
Pope, Simon J. A.
Quinn, Susan
Faulkner, Stephen
Gunnlaugsson, Thorfinnur [1 ]
机构：
[1] Univ Dublin Trinity Coll, Sch Chem, Ctr Synth & Chem Biol, Dublin 2, Ireland
[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
INORGANIC CHEMISTRY | 2006年 / 45卷 / 25期
关键词：
D O I：
10.1021/ic061706i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The development of novel mixed lanthanide-transition-metal (f-d) based supramolecular self-assemblies made from neodymium-and ytterbium-based tetraamide-functionalized cyclen complexes bearing a single 1,10-phenanthroline moiety coordinating to a Ru-II-(bipy)(2) (bipy = bipyridine) unit is described. Excitation of the Ru(II) metal-to-ligand charge-transfer band in water gave rise to long-wavelength sensitized emission from the Yb(III) or Nd(III) centers, observed in the near-infrared.
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收藏
页码：10040 / 10042
页数：3
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