Synthesis of Fe-M complexes (M=Mo, Mn, Fe, Co, Ni, Zn, Cd, Hg) using trans-Fe(EtPhPpy)(2)(CO)(3) as an organometallic tridentate ligand - Molecular structures of (CO)(3)Fe(mu-EtPhPpy)(2)Mo(CO)(3) and (CO)(3)Fe(mu-EtPhPpy)(2)Cd(SCN)(2) (EtPhPpy equals 2-(ethylphenylphosphino)pyridine)

被引：25

作者：

Kuang, SM

Zhang, ZZ

Wu, BM

Mak, TCW

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHATIN,NT,HONG KONG

[2] NANKAI UNIV,ELEMENTOORGAN CHEM LAB,TIANJIN 300071,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 540卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

2-(ethylphenylphosphino)pyridine; heterodinuclear complex; molecular structure;

D O I：

10.1016/S0022-328X(97)00114-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

trans-Fe(EtPhPpy)(2)(CO)(3) reacts with Mo(CO)(6) and M(SCN)(2) (M = Mn, Fe, Co, Ni, Zn, Cd, Hg) to form binuclear complexes containing an Fe-M bond. Crystal and molecular structures of the title complexes have been determined by X-ray analysis, which yielded Fe(0)-Mo(0) and Fe(0)-Cd(II) bonded lengths of 2.922(1)Angstrom and 2.648(1)Angstrom respectively. (C) 1997 Elsevier Science S.A.

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页码：55 / 60

页数：6

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