Photo- and electro-catalysis for solar disinfection of Escherichia coli-contaminated water using Ag-TiO2/graphite

被引:13
作者
Rahmawati, Fitria [1 ]
Kusumaningsih, Triana [2 ]
Hastuti, Aris [1 ]
机构
[1] Sebelas Maret Univ, Dept Chem, Res Grp Phys Chem, Surakarta 57772, Indonesia
[2] Sebelas Maret Univ, Dept Chem, Biochem Res Grp, Surakarta 57772, Indonesia
关键词
photo catalysis; electro catalysis; Escherichia coli; solar disinfection; Ag-TiO2/Graphite; BACTERICIDAL ACTIVITY; BACILLUS-SUBTILIS; TITANIUM-DIOXIDE; TIO2; DNA; INACTIVATION; DEGRADATION; SUSPENSIONS; FILM;
D O I
10.1080/02772248.2011.604322
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A titanium dioxide film on a graphite substrate was synthesized by chemical bath deposition from TiCl4 as precursor and with the surfactant cetyl trimethyl ammonium bromide as a linking and assembling agent. Silver was loaded on the TiO2 film by electrodeposition at 0.025 A. Water contaminated with Escherichia coli was disinfected under sunlight irradiation by photolysis (Lys), photocatalysis (PC), photoelectrocatalysis (PEC), and electrocatalysis (EC). The highest rate constant, k, was achieved with EC; k was 5.1 x 10(-2) colony forming units (CFU) mL(-1) min(-1). However, auto-oxidation of Ag occurred during EC and PEC. Meanwhile, the rate constant of disinfection by means of PC was lower than EC and PEC, and k was 3.82 x 10(-2) CFU mL(-1) min(-1). Nevertheless, the auto-oxidation of Ag in the Ag-TiO2/graphite tablet did not occur during the disinfection process.
引用
收藏
页码:1602 / 1612
页数:11
相关论文
共 31 条
[1]  
ACRA A, 1980, LANCET, V2, P1257
[2]   PHOTOCATALYTIC HYDROGENATION OF CH3CCH WITH H2O ON SMALL-PARTICLE TIO2 - SIZE QUANTIZATION EFFECTS AND REACTION INTERMEDIATES [J].
ANPO, M ;
SHIMA, T ;
KODAMA, S ;
KUBOKAWA, Y .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (16) :4305-4310
[3]  
Belapurkar AD, 2006, CURR SCI INDIA, V91, P73
[4]   Application of the photocatalytic chemistry of titanium dioxide to disinfection and the killing of cancer cells [J].
Blake, DM ;
Maness, PC ;
Huang, Z ;
Wolfrum, EJ ;
Huang, J ;
Jacoby, WA .
SEPARATION AND PURIFICATION METHODS, 1999, 28 (01) :1-50
[5]   Solar photocatalytic detoxification and disinfection of water:: Recent overview [J].
Blanco-Galvez, Julian ;
Fernandez-Ibanez, Pilar ;
Malato-Rodriguez, Sixto .
JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME, 2007, 129 (01) :4-15
[6]   Bactericidal effect of solar water disinfection under real sunlight conditions [J].
Boyle, M. ;
Sichel, C. ;
Fernandez-Ibanez, P. ;
Arias-Quiroz, G. B. ;
Iriarte-Puna, M. ;
Mercado, A. ;
Ubomba-Jaswa, E. ;
McGuigan, K. G. .
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 2008, 74 (10) :2997-3001
[7]   Water disinfection using an immobilised titanium dioxide film in a photochemical reactor with electric field enhancement [J].
Butterfield, IM ;
Christensen, PA ;
Curtis, TP ;
Gunlazuardi, J .
WATER RESEARCH, 1997, 31 (03) :675-677
[8]   Photoelectrocatalytic and photocatalytic disinfection of E-coli suspensions by titanium dioxide [J].
Christensen, PA ;
Curtis, TP ;
Egerton, TA ;
Kosa, SAM ;
Tinlin, JR .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 41 (04) :371-386
[9]   The photocatalytic removal of bacterial pollutants from drinking water [J].
Dunlop, PSM ;
Byrne, JA ;
Manga, N ;
Eggins, BR .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) :355-363
[10]   Photoelectrocatalytic disinfection of E. coli suspensions by iron doped TiO2 [J].
Egerton, TA ;
Kosa, SAM ;
Christensen, PA .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (03) :398-406