4-Methylanilinium perchlorate 18-crown-6 clathrate

被引：0

作者：

Wang, Yu-Feng ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

Data-to-parameter ratio = 18.2; Mean σ(C-C) = 0.003 Å; R factor = 0.052; Single-crystal X-ray study; T = 293 K; wR factor = 0.131;

D O I：

10.1107/S1600536811053992

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C(7)H(10)N(+)center dot ClO(4)(-)center dot C(12)H(24)O(6), the 4-methylanilinium cation interacts with an 18-crown-6 molecule forming a rotator-stator-like structure through bifurcated N-H center dot center dot center dot(O, O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether molecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)degrees.

引用

页数：8