Perovskite-type hydrides-synthesis, structures and properties

被引：47
作者：
Ikeda, Kazutaka [1 ]
Sato, Toyoto [1 ]
Orimo, Shin-ichi [1 ]
机构：
[1] Tohoku Univ, Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan
来源：
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH | 2008年 / 99卷 / 05期
关键词：
hydrogen; hydrides; perovskites; chemical bonding; transformation;
D O I：
10.3139/146.101671
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
The present study gives an overview of the fundamental material properties of perovskite-type hydrides. Formation ability of the perovskite-type hydrides has been reasonably explained on the basis of the geometric restrictions on the composed ions using the Goldschmidt tolerance factor. Characteristic crystal structures and charge density maps of the perovskite-type hydrides without/with transition metals, such as NaMgH3/CaNiH3, were also examined in detail to clarify the relationship between the structures (atomic and electronic) and the hydriding properties.
引用
收藏
页码：471 / 479
页数：9
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