High quality nano-patterned thin films of the coordination compound {Fe(pyrazine)[Pt(CN)4]} deposited layer-by-layer

被引：52

作者：

Bartual-Murgui, Carlos ^{[1
,2
]}

Salmon, Lionel ^{[1
,2
]}

Akou, Amal ^{[1
,2
]}

Thibault, Christophe ^{[3
,4
]}

Molnar, Gabor ^{[1
,2
]}

Mahfoud, Tarik ^{[1
,5
]}

Sekkat, Zouheir ^{[5
,6
]}

Antonio Real, Jose ^{[7
]}

Bousseksou, Azzedine ^{[1
,2
]}

机构：

[1] CNRS, LCC, F-31077 Toulouse, France

[2] Univ Toulouse, UPS, INP, F-31077 Toulouse, France

[3] CNRS, LAAS, F-31077 Toulouse, France

[4] Univ Toulouse, UPS, INSA, ISAE, F-31077 Toulouse, France

[5] Moroccan Fdn Sci Innovat & Res MAScIR, OPC, Technopolis Rabatshore, Morocco

[6] Hassan II Acad Sci & Technol, Rabat, Morocco

[7] Univ Valencia, Inst Ciencia Mol ICMol, Valencia 46980, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 10期

关键词：

SPIN-CROSSOVER NANOPARTICLES; ROOM-TEMPERATURE; THERMAL HYSTERESIS; TRANSITION; FRAMEWORKS; PARTICLE;

D O I：

10.1039/c1nj20212j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An optimised procedure was developed for the layer-by-layer deposition of the Hofmann clathrate-like coordination compound {Fe(pyrazine)[Pt(CN)(4)]} either as continuous or as nano-patterned thin films. Characterization of the thickness and topography of the thin films by atomic force microscopy (AFM) and by surface plasmon resonance (SPR) spectroscopy, which also yields the layer's refractive index and losses, are reported. We found that the films are of good optical quality and the results of both AFM and SPR experiments are in good agreement with the theoretical predictions of the films thicknesses.

引用

收藏

页码：2089 / 2094

页数：6

相关论文

共 24 条

[1] Thermal and Light-Induced Spin Crossover Phenomena in New 3D Hofmann-Like Microporous Metalorganic Frameworks Produced As Bulk Materials and Nanopatterned Thin Films [J].

Agusti, Gloria ;

Cobo, Saioa ;

Gaspar, Ana B. ;

Molnar, Gabor ;

Moussa, Nawel Ould ;

Szilagyi, Petra A. ;

Palfi, Villoe ;

Vieu, Christophe ;

Munoz, M. Carmen ;

Real, Jose Antonio ;

Bousseksou, Azzedine .

CHEMISTRY OF MATERIALS, 2008, 20 (21) :6721-6732

[2] Oxidative Addition of Halogens on Open Metal Sites in a Microporous Spin-Crossover Coordination Polymer [J].

Agusti, Gloria ;

Ohtani, Ryo ;

Yoneda, Ko ;

Gaspar, Ana B. ;

Ohba, Masaaki ;

Sanchez-Royo, Juan F. ;

Carmen Munoz, M. ;

Kitagawa, Susumu ;

Real, Jose A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8944-8947

[3] Observation of an asymmetry in the thermal hysteresis loop at the scale of a single spin-crossover particle [J].

Arnaud, Carole ;

Forestier, Thibaut ;

Daro, Nathalie ;

Freysz, Eric ;

Letard, Jean-Francois ;

Pauliat, Gilles ;

Roosen, Gerald .

CHEMICAL PHYSICS LETTERS, 2009, 470 (1-3) :131-135

[4] GROWTH OF LAMELLAR HOFMANN CLATHRATE FILMS BY SEQUENTIAL LIGAND-EXCHANGE REACTIONS - ASSEMBLING A COORDINATION SOLID ONE-LAYER AT A TIME [J].

BELL, CM ;

ARENDT, MF ;

GOMEZ, L ;

SCHMEHL, RH ;

MALLOUK, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :8374-8375

[5] Spin-crossover nanocrystals with magnetic, optical, and structural bistability near room temperature [J].

Boldog, Ishtvan ;

Gaspar, Ana B. ;

Martinez, Victor ;

Pardo-Ibanez, Pablo ;

Ksenofontov, Vadim ;

Bhattacharjee, Ashis ;

Guetlich, Philipp ;

Real, Jose A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (34) :6433-6437

[6] Functional Coordination Nanoparticles [J].

Catala, Laure ;

Volatron, Florence ;

Brinzei, Daniela ;

Mallah, Talal .

INORGANIC CHEMISTRY, 2009, 48 (08) :3360-3370

[7] Micro- and Nanopatterning of Spin-Transition Compounds into Logical Structures [J].

Cavallini, Massimiliano ;

Bergenti, Ilaria ;

Milita, Silvia ;

Ruani, Giampiero ;

Salitros, Ivan ;

Qu, Zhi-Rong ;

Chandrasekar, Rajadurai ;

Ruben, Mario .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (45) :8596-8600

[8] Single-laser-shot-induced complete bidirectional spin transition at room temperature in single crystals of (FeII(pyrazine)(Pt(CN)4)) [J].

Cobo, Saioa ;

Ostrovskii, Denis ;

Bonhommeau, Sebastien ;

Vendier, Laure ;

Molnar, Gabor ;

Salmon, Lionel ;

Tanaka, Koichiro ;

Bousseksou, Azzedine .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (28) :9019-9024

[9] Multilayer sequential assembly of thin films that display room-temperature spin crossover with hysteresis [J].

Cobo, Saioa ;

Molnar, Gabor ;

Real, Jose Antonio ;

Bousseksou, Azzedine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5786-5789

[10] Bistable spin-crossover nanoparticles showing magnetic thermal hysteresis near room temperature [J].

Coronado, Eugenio ;

Galan-Mascaros, Jose Ramon ;

Monrabal-Capilla, Maria ;

Garcia-Martinez, Javier ;

Pardo-Ibanez, Pablo .

ADVANCED MATERIALS, 2007, 19 (10) :1359-+