High quality nano-patterned thin films of the coordination compound {Fe(pyrazine)[Pt(CN)4]} deposited layer-by-layer

被引：52
作者：
Bartual-Murgui, Carlos [1 ,2 ]
Salmon, Lionel [1 ,2 ]
Akou, Amal [1 ,2 ]
Thibault, Christophe [3 ,4 ]
Molnar, Gabor [1 ,2 ]
Mahfoud, Tarik [1 ,5 ]
Sekkat, Zouheir [5 ,6 ]
Antonio Real, Jose [7 ]
Bousseksou, Azzedine [1 ,2 ]
机构：
[1] CNRS, LCC, F-31077 Toulouse, France
[2] Univ Toulouse, UPS, INP, F-31077 Toulouse, France
[3] CNRS, LAAS, F-31077 Toulouse, France
[4] Univ Toulouse, UPS, INSA, ISAE, F-31077 Toulouse, France
[5] Moroccan Fdn Sci Innovat & Res MAScIR, OPC, Technopolis Rabatshore, Morocco
[6] Hassan II Acad Sci & Technol, Rabat, Morocco
[7] Univ Valencia, Inst Ciencia Mol ICMol, Valencia 46980, Spain
来源：
NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 10期
关键词：
SPIN-CROSSOVER NANOPARTICLES; ROOM-TEMPERATURE; THERMAL HYSTERESIS; TRANSITION; FRAMEWORKS; PARTICLE;
D O I：
10.1039/c1nj20212j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An optimised procedure was developed for the layer-by-layer deposition of the Hofmann clathrate-like coordination compound {Fe(pyrazine)[Pt(CN)(4)]} either as continuous or as nano-patterned thin films. Characterization of the thickness and topography of the thin films by atomic force microscopy (AFM) and by surface plasmon resonance (SPR) spectroscopy, which also yields the layer's refractive index and losses, are reported. We found that the films are of good optical quality and the results of both AFM and SPR experiments are in good agreement with the theoretical predictions of the films thicknesses.
引用
收藏
页码：2089 / 2094
页数：6
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