Photocatalytic activities of C-N-doped TiO2 nanotube array/carbon nanorod composite

被引:109
作者
Liu, Shaohuan [1 ]
Yang, Lixia [1 ]
Xu, Shihai [1 ]
Luo, Shenglian [1 ]
Cai, Qingyun [1 ]
机构
[1] Hunan Univ, Dept Chem, State Key Lab Chemobiosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
基金
美国国家科学基金会;
关键词
C-N-doped TiO2 nanotube; Carbon nanorod; Photocurrent; Photocatalyst; ARRAYS; FABRICATION;
D O I
10.1016/j.elecom.2009.07.007
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A C-N-doped TiO2 nanotube (NT)/carbon nanorod composite is fabricated by chemical vapor deposition (CVD). Carbon nanorods are grown from the TiO2 NTs, and partly graphitized, while TiO2 is in the mixture of anatase and rutile. The C-N doping shifts the absorption edge of TiO2 NTs to the visible light region; the formed carbon nanorods promote the charge carrier transfer from the TiO2 surface to the electrolyte. Under the simulated solar light irradiation, the C-N-doped TiO2 NTs show higher photocatalytic activity in the degradation of methyl orange (MO) than the undoped TiO2 NTS. (C) 2009 Published by Elsevier B.V.
引用
收藏
页码:1748 / 1751
页数:4
相关论文
共 17 条
  • [1] Visible-light photocatalysis in nitrogen-doped titanium oxides
    Asahi, R
    Morikawa, T
    Ohwaki, T
    Aoki, K
    Taga, Y
    [J]. SCIENCE, 2001, 293 (5528) : 269 - 271
  • [2] Structural and optical properties of titanium oxide thin films deposited by filtered arc deposition
    Bendavid, A
    Martin, PJ
    Jamting, Å
    Takikawa, H
    [J]. THIN SOLID FILMS, 1999, 355 : 6 - 11
  • [3] Nitrogen-doped TiO2 from TiN and its visible light photoelectrochemical properties
    Cui, Xiaoli
    Ma, Ming
    Zhang, Wei
    Yang, Yanchao
    Zhang, Zhuangjian
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (03) : 367 - 371
  • [4] Ion implantation and annealing for an efficient N-doping of TiO2 nanotubes
    Ghicov, Andrei
    Macak, Jan M.
    Tsuchiya, Hiroaki
    Kunze, Julia
    Haeublein, Volker
    Frey, Lothar
    Schmuki, Patrik
    [J]. NANO LETTERS, 2006, 6 (05) : 1080 - 1082
  • [5] Dye-sensitized solar cells
    Grätzel, M
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) : 145 - 153
  • [6] Grimes CA, 2009, TIO2 NANOTUBE ARRAYS - SYNTHESIS, PROPERTIES, AND APPLICATIONS, pXIII
  • [7] Fabrication and catalytic properties of Pt and Ru decorated TiO2\CNTs catalyst for methanol electrooxidation
    He, Dongmei
    Yang, Lixia
    Kuang, Shuyun
    Cai, Qingyun
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (10) : 2467 - 2472
  • [8] ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS
    HOFFMANN, MR
    MARTIN, ST
    CHOI, WY
    BAHNEMANN, DW
    [J]. CHEMICAL REVIEWS, 1995, 95 (01) : 69 - 96
  • [9] Fabrication of carbon-modified TiO2 nanotube arrays and their photocatalytic activity
    Hu, Xiaoye
    Zhang, Tianci
    Jin, Zhen
    Zhang, Junxi
    Xu, Wei
    Yan, Jian
    Zhang, Jinping
    Zhang, Lide
    Wu, Yucheng
    [J]. MATERIALS LETTERS, 2008, 62 (30) : 4579 - 4581
  • [10] Single wall carbon nanotube scaffolds for photoelectrochemical solar cells.: Capture and transport of photogenerated electrons
    Kongkanand, Anusorn
    Dominguez, Rebeca Martinez
    Kamat, Prashant V.
    [J]. NANO LETTERS, 2007, 7 (03) : 676 - 680