A facile synthesis of (+/-)-mintlactone

被引：11
作者：
Tanyeli, C
Caliskan, Z
Demir, AS
机构：
[1] Department of Chemistry, Middle East Technical University
来源：
SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 19期
关键词：
D O I：
10.1080/00397919708005649
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
(+/-)-Mintlactone has been synthesized by applying a novel effective synthetic sequence. 4-Methylcyclohexanone was subjected to acetoxylation with Pb(OAc)(4). Hydrolysis followed by reaction with 2-chloroprogionyl chloride,then treatment with triethyl phosphite and, finally, Horner-Emmons-type intramolecular cyclization afforded (+/-)-Mintlactone.
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页码：3471 / 3476
页数：6
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