Local and global electrochemical impedances applied to the corrosion behaviour of an AZ91 magnesium alloy

被引:171
作者
Galicia, Gonzalo [1 ]
Pebere, Nadine [2 ]
Tribollet, Bernard [1 ]
Vivier, Vincent [1 ]
机构
[1] Univ Paris 06, CNRS, LISE UPR 15, F-75252 Paris 05, France
[2] Univ Toulouse, CIRIMAT, UPS INPT CNRS, ENSIACET, F-31077 Toulouse 04, France
关键词
Alloy; Magnesium; EIS; SCANNING VIBRATING ELECTRODE; PHASE-ELEMENT BEHAVIOR; SODIUM-SULFATE SOLUTIONS; PITTING CORROSION; STAINLESS-STEELS; PURE MAGNESIUM; DISK ELECTRODE; SPECTROSCOPY; CHLORIDE; PERFORMANCE;
D O I
10.1016/j.corsci.2009.05.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electrochemical behaviour of an AZ91 magnesium alloy was investigated in a low aggressive medium by means of local and global electrochemical impedance measurements. The results were compared to those obtained on a pure magnesium sample. It was possible to show the individual contribution of each phase constituting the alloy, and it was observed that the corrosion mechanism of the two phases was the same, controlled by the Mg dissolution. However, local impedance diagrams clearly indicated that the kinetics dissolution of the beta-phase was slower than that of the alpha-phase, which was in good agreement with SEM observations. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1789 / 1794
页数:6
相关论文
共 34 条
[1]   Localized electrochemical impedance spectroscopy for studying pitting corrosion on stainless steels [J].
Annergren, I ;
Thierry, D ;
Zou, F .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :1208-1215
[2]  
Bard A.J., 2001, ELECTROCHEMICAL METH
[3]   Local electrochemical impedance spectroscopy applied to the corrosion behavior of an AZ91 magnesium alloy [J].
Baril, G ;
Blanc, C ;
Keddam, M ;
Pébère, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (10) :B488-B493
[4]   The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions [J].
Baril, G ;
Pébère, N .
CORROSION SCIENCE, 2001, 43 (03) :471-484
[5]   AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys -: Characterization with respect to their microstructures [J].
Baril, G ;
Blanc, C ;
Pébère, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (12) :B489-B496
[6]   An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions [J].
Baril, Genevieve ;
Galicia, Gonzalo ;
Deslouis, Claude ;
Pebere, Nadine ;
Tribollet, Bernard ;
Vivier, Vincent .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) :C108-C113
[7]   Local electrochemical impedance measurement: scanning vibrating electrode technique in ac mode [J].
Bayet, E ;
Huet, F ;
Keddam, M ;
Ogle, K ;
Takenouti, H .
ELECTROCHIMICA ACTA, 1999, 44 (24) :4117-4127
[8]   A novel way of measuring local electrochemical impedance using a single vibrating probe [J].
Bayet, E ;
Huet, F ;
Keddam, M ;
Ogle, K ;
Takenouti, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :L87-L90
[9]   HIGH-PERFORMANCE AEROSPACE ALLOYS VIA RAPID SOLIDIFICATION PROCESSING [J].
DAS, SK ;
DAVIS, LA .
MATERIALS SCIENCE AND ENGINEERING, 1988, 98 :1-12
[10]   Probing of local dissolution of Al-alloys in chloride solutions by AFM and SECM [J].
Davoodi, A. ;
Pan, J. ;
Leygraf, C. ;
Norgren, S. .
APPLIED SURFACE SCIENCE, 2006, 252 (15) :5499-5503