Chiral bis(oxazolinyl)phenyl rhodium and palladium complexes

被引：94

作者：

Motoyama, Y ^{[1
]}

Makihara, N ^{[1
]}

Mikami, Y ^{[1
]}

Aoki, K ^{[1
]}

Nishiyama, H ^{[1
]}

机构：

[1] TOYOHASHI UNIV TECHNOL, SCH MAT SCI, TOYOHASHI, AICHI 441, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 09期

关键词：

D O I：

10.1246/cl.1997.951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transmetalation of Phebox-ip-SnMe3 [Phebox = 2,6-bis(oxazolinyl)phenyl] 1c with RhCl3(H2O)(3) and PdCl2(PhCN)(2) gave (Phebox-ip)RhCl2(H2O) 2a and (Phebox-ip)PdCl 3 under mild conditions in 45% and 96% yields, respectively. The crystal structures of (Phebox-ip)Rh Cl-2(t-BuNC) 2b, which was obtained by the reaction of 2a with t-BuNC, and 3 have bees determined by X-ray diffraction.

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页码：951 / 952

页数：2

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