Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

被引：237
|
作者：
Wu, Jessica Y. [1 ]
Moreau, Benoit [1 ]
Ritter, Tobias [1 ]
机构：
[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 36期
关键词：
TRANSITION-METAL-COMPLEXES; CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; ALLYLIC ALCOHOLS; ORGANIC-SYNTHESIS; LIGANDS; CYCLOISOMERIZATION; HYDROBORATIONS; CATECHOLBORANE; ALLYLBORATION;
D O I：
10.1021/ja9048493
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords gamma-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.
引用
收藏
页码：12915 / +
页数：4
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