Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

被引：236

作者：

Wu, Jessica Y. ^{[1
]}

Moreau, Benoit ^{[1
]}

Ritter, Tobias ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 36期

关键词：

TRANSITION-METAL-COMPLEXES; CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; ALLYLIC ALCOHOLS; ORGANIC-SYNTHESIS; LIGANDS; CYCLOISOMERIZATION; HYDROBORATIONS; CATECHOLBORANE; ALLYLBORATION;

D O I：

10.1021/ja9048493

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords gamma-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.

引用

页码：12915 / +

页数：4