Rapid response concentration-controlled desorption of activated carbon to dampen concentration fluctuations

被引:23
作者
Hashisho, Zaher
Emamipour, Hamidreza
Cevallos, Diego
Rood, Mark J.
Hay, K. James
Kim, Byung J.
机构
[1] Univ Illinois, Dept Civil & Environm Engn, Urbana, IL 61801 USA
[2] Engineer Res & Dev Ctr, Construct Engn Res Lab, Champaign, IL 61826 USA
关键词
D O I
10.1021/es062155y
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Fluctuations in concentration of organic vapors in gas streams that are treated by devices such as biofilters or oxidizers make it challenging to remove the vapors from the gas streams in an efficient and economic manner. Combining adsorption with concentration-controlled desorption provides an active buffer between the source of vapors and the control device for better control of concentration and flow rate of the gas stream that is treated by the secondary control device, hence further enhancing the performance or reducing the size of the devices. Activated carbon fiber cloth is used with microwave swing adsorption to remove methyl ethyl ketone (MEK) from air streams and then provide a readily controllable feed stream of that vapor in air at a specified concentration and gas flow rate with steady-state tracking desorption. MEK was captured with > 99.8% efficiency during the adsorption cycle. The MEK concentration during the regeneration cycle was readily controlled at concentration set-points between 170 and 5000 ppmv, within relative standard deviations of 1.8 and 4.9%, respectively, and at 20% of the gas flow rate that was treated during the adsorption cycle. Such capability of the system allows the secondary control device to be optimized for select constant concentrations and low gas flow rates that is not possible without such pretreatment.
引用
收藏
页码:1753 / 1758
页数:6
相关论文
共 19 条
[1]   Biofiltration of a mixture of volatile organic compounds on granular activated carbon [J].
Aizpuru, A ;
Malhautier, L ;
Roux, JC ;
Fanlo, JL .
BIOTECHNOLOGY AND BIOENGINEERING, 2003, 83 (04) :479-488
[2]  
CAI Z, 2006, A WMAS 99 ANN M EXH
[3]   Adsorption and desorption characteristics of semiconductor volatile organic compounds on the thermal swing honeycomb zeolite concentrator [J].
Chang, FT ;
Lin, YC ;
Bai, HL ;
Pei, BS .
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION, 2003, 53 (11) :1384-1390
[4]   Effect of starvation on the performance and re-acclimation of biotrickling filters for air pollution control [J].
Cox, HHJ ;
Deshusses, MA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (14) :3069-3073
[5]  
Crowl D. A., 2002, Chemical Process Safety: Fundamentals with Applications, Vthird
[6]   Treatment of H2S using a horizontal biotrickling filter based on biological activated carbon:: reactor setup and performance evaluation [J].
Duan, HQ ;
Koe, LCC ;
Yan, R .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2005, 67 (01) :143-149
[7]   Microwave-swing adsorption to capture and recover vapors from air streams with activated carbon fiber cloth [J].
Hashisho, Z ;
Rood, M ;
Botich, L .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (17) :6851-6859
[8]  
Hunter P, 2000, CONTROL VOLATILE ORG
[9]   Behavior of trickle-bed air biofilter for toluene removal: Effect of non-use periods [J].
Kim, D ;
Cai, ZG ;
Sorial, GA .
ENVIRONMENTAL PROGRESS, 2005, 24 (02) :155-161
[10]  
KIM D, 2006, A WMA 99 ANN M EXH N