Triply bridged dicopper-bis(trimethylsilylchalcogenolates):: Synthesis and characterization of the series of helical complexes [(Me3SiE-Cu)2(μ-Ph2PCCPPh2-κ2P)3] (E=S, Se, Te)

被引：13
作者：
Wallbank, AI [1 ]
Corrigan, JF [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2002年 / 80卷 / 11期
关键词：
copper; chalcogen; helical; trimethylsilyl groups; phosphinoacetylene;
D O I：
10.1139/V02-032
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The copper-chalcogenolates [(Me3SiE-Cu)(2)(mu-Ph2PC equivalent to CPPh2-kappa(2)P)(3)] (1, E = S; 2, E = Se; 3, E = Te) have been prepared in good yield from [(OAcCu)(2)(mu-Ph2PC equivalent to CPPh2-kappa(2)P)(3)] and E(SiMe3)(2) at low temperatures. Complexes 1-3 contain two pendant -ESiMe3 moieties bonded to copper(I) centres, which are also bridged by three didentate ligands to form helical structures. Complexes 1-3 have been characterized by single crystal crystallographic and spectroscopic methods.
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页码：1592 / 1599
页数：8
相关论文
共 105 条
[1]  
Abe H, 1998, CHEM PHARM BULL, V46, P1311
[2]   INTERACTION OF THIOSILANES AND DISILTHIANES WITH SOME TRANSITIONAL AND POST-TRANSITIONAL METAL HALIDES [J].
ABEL, EW ;
JENKINS, CR .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 14 (02) :285-&
[3]   New organometallic gallium-chalcogen compounds containing Ga(4)E(4) heterocubanes. Synthesis and crystal structures of [{Cp(CO)(2)Fe}(4)Ga(4)E(4)] (E=S, Se, Te) [J].
App, U ;
Merzweiler, K .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (03) :478-482
[4]   THE CHEMISTRY OF METAL-COMPLEXES WITH SELENOLATE AND TELLUROLATE LIGANDS [J].
ARNOLD, J .
PROGRESS IN INORGANIC CHEMISTRY, VOL 43, 1995, 43 :353-417
[5]   MONONUCLEAR AND DINUCLEAR PHOSPHINE COORDINATED 1,4-BIS(DIPHENYLPHOSPHINO)ETHYNE 7-COORDINATE COMPLEXES OF MOLYBDENUM(II) AND TUNGSTEN(II) [J].
BAKER, PK ;
ARMSTRONG, EM .
POLYHEDRON, 1990, 9 (06) :801-804
[6]   COORDINATIVE PROPERTIES OF CIS-TRANS-1,4-DIPHOSPHABUTENE AND 1,4-DIPHOSPHABUTYNE IN CARBONYLVANADIUM COMPOUNDS [J].
BECHTHOLD, HC ;
REHDER, D .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 172 (03) :331-339
[7]   Synthesis and structure of the nanoclusters [Hg32Se14(SePh)(36)], [Cd32Se14(SePh)(36-)(PPh(3))(4)], [P(Et)(2)(Ph)C(4)H(8)OSiMe(3)](5-)[Cd18I17(PSiMe(3))(12)], and [N(Et)(3)C(4)H(8)OSiMe(3)](5)[Cd18I17(PSiMe(3))(12)] [J].
Behrens, S ;
Bettenhausen, M ;
Deveson, AC ;
Eichhofer, A ;
Fenske, D ;
Lohde, A ;
Woggon, U .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (19) :2215-2218
[8]  
Bettenhausen M, 1998, Z ANORG ALLG CHEM, V624, P1245, DOI 10.1002/(SICI)1521-3749(199808)624:8<1245::AID-ZAAC1245>3.0.CO
[9]  
2-D
[10]   TEMPLATE SYNTHESES OF 1,2-ALKENE DICHALCOGENIDE CHELATES VIA THE ADDITION OF ACTIVATED ACETYLENES TO DICYCLOPENTADIENYLTITANIUM PENTACHALCOGENIDES [J].
BOLINGER, CM ;
RAUCHFUSS, TB .
INORGANIC CHEMISTRY, 1982, 21 (11) :3947-3954
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