Application of α-chloroaldoxime O-methanesulfonates to one-pot synthesis of N,N′,N"-substituted guanidines via Tiemann rearrangement

被引：14
|
作者：
Yamamoto, Yuhei [1 ]
Mizuno, Hiroo [1 ]
Tsuritani, Takayuki [1 ]
Mase, Toshiaki [1 ]
机构：
[1] Banyu Pharmaceut Co Ltd, Proc Res, Preclin Dev, Tsukuba, Ibaraki 3002611, Japan
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 42期
关键词：
Guanidines; alpha-Chloroaldoxime O-methanesulfonates; Tiemann rearrangement; Carbodiimides; LOSSEN REARRANGEMENT; CARBODIIMIDE CHEMISTRY; POTASSIUM-SALTS; BENZIMIDAZOLES; AMIDOXIMES; AMIDINES; ACIDS; DECOMPOSITION; DERIVATIVES; PHASE;
D O I：
10.1016/j.tetlet.2009.07.147
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical one-pot synthesis of N,N',N ''-trisubstituted guanidines via Tiemann rearrangement involving the reaction of alpha-chloroaldoxime O-methanesulfonates with alkyl amines is disclosed. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5813 / 5815
页数：3
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