Oxidative Carbon-Carbon Bond Formation via Allyldimethylsilyl Enol Ethers

被引：12
|
作者：
Konkol, Leah C. [1 ]
Jones, Brian T. [1 ]
Thomson, Regan J. [1 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 23期
基金：
美国国家卫生研究院;
关键词：
SOLVENT-DEPENDENT CHEMOSELECTIVITIES; CERIC AMMONIUM-NITRATE; COUPLING REACTIONS; CATION RADICALS; ALLYLTRIMETHYLSILANE; ALLYLATION; SILICON;
D O I：
10.1021/ol902400q
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers Is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.
引用
收藏
页码：5550 / 5553
页数：4
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