Oxidative Carbon-Carbon Bond Formation via Allyldimethylsilyl Enol Ethers

被引：13

作者：

Konkol, Leah C. ^{[1
]}

Jones, Brian T. ^{[1
]}

Thomson, Regan J. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 23期

基金：

美国国家卫生研究院;

关键词：

SOLVENT-DEPENDENT CHEMOSELECTIVITIES; CERIC AMMONIUM-NITRATE; COUPLING REACTIONS; CATION RADICALS; ALLYLTRIMETHYLSILANE; ALLYLATION; SILICON;

D O I：

10.1021/ol902400q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers Is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.

引用

页码：5550 / 5553

页数：4

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