Influence of single-walled carbon nanotubes induced crystallinity enhancement and morphology change on polymer photovoltaic devices

被引：210

作者：

Geng, Jianxin ^{[1
]}

Zeng, Tingying ^{[1
]}

机构：

[1] Western Kentucky Univ, Dept Chem, Lab Nanostruct, Bowling Green, KY 42101 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 51期

关键词：

D O I：

10.1021/ja065035z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-walled carbon nanotubes (SWNTs) were determined to have significant interaction with poly(3-hexylthiophene) (P3HT), which is helpful to form continuous active film with interpenetrating structure and improve the crystallinity of the resultant film for SWNTs/P3HT composite. Photovoltaic devices based on an active film with relatively higher crystallinity display much enhanced performance. The work function of carbon nanotubes modulated by electron transferring from P3HT to SWNTs is proposed to explain the high open-circuit voltage (V-OC) obtained from the photovoltaic devices based on the SWNTs/P3HT system.

引用

页码：16827 / 16833

页数：7

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