Solid-state phase transformations in solution: templated conversion of nanoscale nickel phosphides

被引：26

作者：

Muthuswamy, Elayaraja ^{[1
]}

Brock, Stephanie L. ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 45期

基金：

美国国家科学基金会;

关键词：

TRANSITION-METAL PHOSPHIDES; GENERAL STRATEGY; NANOPARTICLES; NANOCRYSTALS; NANOWIRES; REACTIVITY; COMPLEXES; CHEMISTRY; FEP;

D O I：

10.1039/c1cc15198c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conversion of Ni12P5 nanoparticles to Ni2P is demonstrated to occur via a solid-state, rather than a solution dissolution, process. The templated transformation is employed to make monodisperse hollow or solid particles of the catalytically active phase Ni2P with surface areas of similar to 17 m(2) g(-1).

引用

页码：12334 / 12336

页数：3

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