Triplet π-diradical dication of directly meso-β-linked porphyrin dimer

被引：29

作者：

Segawa, H ^{[1
]}

Senshu, Y ^{[1
]}

Nakazaki, J ^{[1
]}

Susumu, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Chem, Meguro Ku, Tokyo 1538902, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 05期

关键词：

D O I：

10.1021/ja0385989

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Directly linked bisporphyrin, Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin, was investigated on the basis of the magnetic property of its bis(π-radical cation). A stable triplet state of the bis(π-radical cation) of the bisporphyrin, which obeys the Curie law, was successfully observed. Copyright © 2004 American Chemical Society.

引用

页码：1354 / 1355

页数：2

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