Cluster-containing carbon-rich molecules:: Reactions of ruthenium cluster carbonyls with {Au(PR3)}2(μCCCCC (R = Ph, tol)

被引：13

作者：

Bruce, MI ^{[1
]}

Zaitseva, NN

Skelton, BW

White, AH

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[2] Univ Western Australia, Crawley, WA 6009, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 13期

基金：

澳大利亚研究理事会;

关键词：

carbon-rich; cluster; gold; ruthenium; X-ray;

D O I：

10.1016/j.jorganchem.2005.04.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes containing C-4 ligands attached to one or two AuRu3 clusters by conventional sigma, 2 pi interactions have been obtained from reactions between (R3P)AuC equivalent to CC equivalent to CAu(PR3) (R = Ph, tol) or Au(C equivalent to CC equivalent to CH){P(tol)(3)} and either Ru-3(CO)(12), Ru-3(CO)(10)(NCMe)(2) or Ru-3(mu-dppm)(CO)(10). The X-ray determined structures of {(R3P)AuRu3(CO)(9)}(2)(mu(3),eta(2):mu(3),eta(2)-C2C2) [R = Ph (1) (three solvates), tol (2)], AuRu3{mu(3),eta(2)-C2C equivalent to CAu(PPh3)}(CO)(9)(PPh3) (3) and {(Ph3P)AuRu3(mu-dppm)(CO)(7)} (mu(3), eta(2): mu(3), eta(2)-C2C2){Ru-3(mu-H)(mu-dppm)(CO)(7)} (4) are reported. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：3268 / 3277

页数：10

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