Synthesis of Oxidized Thienopyrroles using HOF•CH3CN

被引：17

作者：

Shefer, Neta ^{[1
]}

Rozen, Shlomo ^{[1
]}

机构：

[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 11期

基金：

以色列科学基金会;

关键词：

ELEMENTAL FLUORINE; EFFICIENT ROUTE; OXIDATION; NITRO; HOF-CH3CN; CHEMISTRY; HOF.CH3CN; ANALOGS; MECN;

D O I：

10.1021/jo200534p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient transformation of the sulfur atoms to the sulfonyl group in a range of thienopyrroles was achieved by using the HOF center dot CH3CN complex. Mild conditions, high yields, and easy purification are the main features of this novel route. Most new materials exhibit considerable red-shift absorptions in the UV/visible range relative to the parent compounds.

引用

页码：4611 / 4616

页数：6

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