Discharge behavior of lithium/sulfur cell with TEGDME based electrolyte at low temperature

被引：139
|
作者：
Ryu, Ho-Suk [1 ]
Ahn, Hyo-Jun [1 ]
Kim, Ki-Won [1 ]
Ahn, Jou-Hyun [1 ]
Cho, Kwon-Koo [1 ]
Nam, Tae-Hyun [1 ]
Kim, Jong-Uk [1 ]
Cho, Gyu-Bong [1 ]
机构：
[1] Gyeongsang Natl Univ, Informat Technol Res Ctr Energy Storage & Convers, Div Adv Mat Sci & Engn, Jinju 660701, South Korea
来源：
JOURNAL OF POWER SOURCES | 2006年 / 163卷 / 01期
关键词：
low temperature; Li/S cell; liquid electrolyte; TEGDME; DOXL; MA;
D O I：
10.1016/j.jpowsour.2005.12.061
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The low temperature behaviors of Li/TEGDNM/S cell was examined using discharge curves, SEM and impedance spectra. The first discharge capacity of Li/S cell with tetra(ethylene glycol) dimethyl ether (TEGDME) electrolyte was 1303 mAh g(-1)-sulfur at 20 degrees C, but 357 mAh g(-1)-sulfur at low temperature of -10 degrees C. The low temperature discharge characteristic is improved by adding 1,3-dioxolane (DOXL) and methylacetate (MA) to TEGDME electrolyte. The optimum composition of mixed electrolyte is MA-DOXL-TEGDME (5:47.5:47:5, v/v). The Li/S cell using the optimum electrolyte has the first discharge capacity of 994 and 1342 mAh g(-1)-S at -10 and 20 degrees C, respectively. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：201 / 206
页数：6
相关论文
共 50 条
  • [1] Effect of various lithium salts in TEGDME based electrolyte for Li/pyrite battery
    Choi, Jae-Won
    Cheruvally, Gouri
    Shin, Yong-Jo
    Ahn, Hyo Jun
    Kim, Ki Won
    Ahn, Jou Hyeon
    ADVANCES IN NANOMATERIALS AND PROCESSING, PTS 1 AND 2, 2007, 124-126 : 971 - +
  • [2] Low Temperature Discharge Cycle Tests for a Lithium Ion Cell
    Jaguemont, J.
    Boulon, L.
    Dube, Y.
    Poudrier, D.
    2014 IEEE VEHICLE POWER AND PROPULSION CONFERENCE (VPPC), 2014,
  • [3] Tuning of electrolyte solvation structure for low-temperature operation of lithium-sulfur batteries
    Kim, Sejin
    Jung, Jinkwan
    Kim, Ilju
    Kwon, Hyeokjin
    Cho, Hannah
    Kim, Hee-Tak
    ENERGY STORAGE MATERIALS, 2023, 59
  • [4] Electrolyte Design for Low Temperature Lithium-Sulfur Battery: From Different Polysulfide Conversion Mechanisms
    Chen, Ying
    Wang, Bao
    Zhang, Zhuangzhuang
    Huang, Yudai
    Li, Bao
    BATTERIES & SUPERCAPS, 2025, 8 (02)
  • [5] Does the sulfur cathode require good mixing for a liquid electrolyte lithium/sulfur cell?
    Zhang, Sheng S.
    ELECTROCHEMISTRY COMMUNICATIONS, 2013, 31 : 10 - 12
  • [6] A low-temperature electrolyte for lithium-ion batteries
    Li, Shiyou
    Li, Xiaopeng
    Liu, Jinliang
    Shang, Zhichao
    Cui, Xiaoling
    IONICS, 2015, 21 (04) : 901 - 907
  • [7] A low-temperature electrolyte for lithium-ion batteries
    Shiyou Li
    Xiaopeng Li
    Jinliang Liu
    Zhichao Shang
    Xiaoling Cui
    Ionics, 2015, 21 : 901 - 907
  • [8] A review on electrode and electrolyte for lithium ion batteries under low temperature
    Li, Yuxuan
    Zheng, Guoxu
    Liu, Guanzuo
    Yuan, Zhuo
    Huang, Xinzhe
    Li, Yinan
    ELECTROANALYSIS, 2023, 35 (09)
  • [9] Concentration Controlling of Carboxylic Ester-Based Electrolyte for Low Temperature Lithium-Ion Batteries
    Gao, Song
    Wang, Kang
    Wang, Liying
    Yang, Xijia
    Yang, Yue
    Xiu, Wencui
    Li, Xuesong
    Lu, Wei
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (54)
  • [10] Fabrication and electrochemical behavior of a lithium-sulfur cell with a TiO2-sulfur-carbon aerogel-based cathode
    He, Yongwei
    Fu, Zhibing
    Zhou, Qingxiao
    Zhong, Minglong
    Yuan, Lei
    Wei, Jianjun
    Yang, Xi
    Wang, Chaoyang
    Zeng, Yong
    IONICS, 2015, 21 (11) : 3065 - 3073
12345