A high-power and fast charging Li-ion battery with outstanding cycle-life

被引:44
作者
Agostini, M. [1 ,4 ]
Brutti, S. [2 ,3 ]
Navarra, M. A. [4 ]
Panero, S. [4 ]
Reale, P. [5 ]
Matic, A. [1 ]
Scrosati, B. [6 ]
机构
[1] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
[2] CNR ISC, UOS Sapienza, Piazzale A Moro 5, I-00185 Rome, Italy
[3] Univ Basilicata, Dipartimento Sci, Vle Ateneo Lucano 10, I-85100 Potenza, Italy
[4] Sapienza Univ Roma, Dipartimento Chim, Ple Aldo Moro 5, I-00185 Rome, Italy
[5] ENEA Ctr Ric Casaccia, Via Anguillarese, I-00100 Rome, Italy
[6] HIU, Ulm, Germany
关键词
LITHIUM-ION; IRREVERSIBLE CAPACITY; CATHODE MATERIALS; LINI0.5MN1.5O4; MITIGATION; NANOTUBES; PROGRESS; SURFACE; ANODE;
D O I
10.1038/s41598-017-01236-y
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Electrochemical energy storage devices based on Li-ion cells currently power almost all electronic devices and power tools. The development of new Li-ion cell configurations by incorporating innovative functional components (electrode materials and electrolyte formulations) will allow to bring this technology beyond mobile electronics and to boost performance largely beyond the state-of-theart. Here we demonstrate a new full Li-ion cell constituted by a high-potential cathode material, i.e. LiNi0.5Mn1.5O4, a safe nanostructured anode material, i.e. TiO2, and a composite electrolyte made by a mixture of an ionic liquid suitable for high potential applications, i.e. Pyr(1),4PF6, a lithium salt, i.e. LiPF6, and standard organic carbonates. The final cell configuration is able to reversibly cycle lithium for thousands of cycles at 1000 mAg(-1) and a capacity retention of 65% at cycle 2000.
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页数:7
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