共 25 条
A high-power and fast charging Li-ion battery with outstanding cycle-life
被引:44
作者:
Agostini, M.
[1
,4
]
Brutti, S.
[2
,3
]
Navarra, M. A.
[4
]
Panero, S.
[4
]
Reale, P.
[5
]
Matic, A.
[1
]
Scrosati, B.
[6
]
机构:
[1] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
[2] CNR ISC, UOS Sapienza, Piazzale A Moro 5, I-00185 Rome, Italy
[3] Univ Basilicata, Dipartimento Sci, Vle Ateneo Lucano 10, I-85100 Potenza, Italy
[4] Sapienza Univ Roma, Dipartimento Chim, Ple Aldo Moro 5, I-00185 Rome, Italy
[5] ENEA Ctr Ric Casaccia, Via Anguillarese, I-00100 Rome, Italy
[6] HIU, Ulm, Germany
来源:
关键词:
LITHIUM-ION;
IRREVERSIBLE CAPACITY;
CATHODE MATERIALS;
LINI0.5MN1.5O4;
MITIGATION;
NANOTUBES;
PROGRESS;
SURFACE;
ANODE;
D O I:
10.1038/s41598-017-01236-y
中图分类号:
O [数理科学和化学];
P [天文学、地球科学];
Q [生物科学];
N [自然科学总论];
学科分类号:
07 ;
0710 ;
09 ;
摘要:
Electrochemical energy storage devices based on Li-ion cells currently power almost all electronic devices and power tools. The development of new Li-ion cell configurations by incorporating innovative functional components (electrode materials and electrolyte formulations) will allow to bring this technology beyond mobile electronics and to boost performance largely beyond the state-of-theart. Here we demonstrate a new full Li-ion cell constituted by a high-potential cathode material, i.e. LiNi0.5Mn1.5O4, a safe nanostructured anode material, i.e. TiO2, and a composite electrolyte made by a mixture of an ionic liquid suitable for high potential applications, i.e. Pyr(1),4PF6, a lithium salt, i.e. LiPF6, and standard organic carbonates. The final cell configuration is able to reversibly cycle lithium for thousands of cycles at 1000 mAg(-1) and a capacity retention of 65% at cycle 2000.
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