Rh(I)-catalyzed CO gas-free carbonylative cyclization of organic halides with tethered nucleophiles using aldehydes as a substitute for carbon monoxide

被引：52

作者：

Morimoto, Tsumoru ^{[1
]}

Fujioka, Masahiko ^{[1
]}

Fuji, Koji ^{[1
]}

Tsutsumi, Ken ^{[1
]}

Kakiuchi, Kiyomi ^{[1
]}

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300192, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 1-3期

关键词：

CO gas-free carbonylation; aldehyde; carbonylative cyclization; rhodium catalyst;

D O I：

10.1016/j.jorganchem.2006.08.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The CO gas-free carbonylative cyclization of organic halides, with tethered nitrogen, oxygen, and carbon nucleophiles, with aldehydes as a substitute for carbon monoxide can be achieved in the presence of a catalytic amount of a rhodium complex. The reaction involves the decarbonylation of the aldehyde by the rhodium catalyst, and the successive carbonylation of an organic halide utilizing the rhodium carbonyl that is formed in situ. Aldehydes having electron-withdrawing groups showed a higher ability to donate the carbonyl moiety. (c) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：625 / 634

页数：10

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