(2-Acetylphenolato)(2,2′-bipyridine)nitratocopper(II)

被引:3
作者
Chen, Li-Hua [1 ]
Zhao, Gan-Qing [1 ]
Wang, Xiang [1 ]
Peng, Qin-Long [1 ]
Pan, Zi-Hong [1 ]
机构
[1] Pingdingshan Univ, Sch Chem & Chem Engn, Pingdingshan 467000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
COPPER(II); NITRATE;
D O I
10.1107/S1600536809042718
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C8H7O2)(NO3)(C10H8N2)], the Cu-II ion is five-coordinate in a distorted square-pyramidal geometry. The basal positions are occupied by two N atoms from a 2,2'-bipyridine ligand and two O atoms from the 2-acetylphenolate anion. The axial position is occupied by one O atom of a nitrate anion. In the bipyridine ligand, the two pyridine rings are slightly twisted by an angle of 3.5 (1)degrees. The crystal structure is stabilized by C-H center dot center dot center dot O hydrogen bonds
引用
收藏
页码:M1427 / U1690
页数:9
相关论文
共 11 条
[1]  
[Anonymous], 2008, APEX2 SAINT
[2]   CRYSTAL STRUCTURES OF BIS-(SALICYLALDEHYDATO)- COPPER(II) AND BIS-(8-HYDROXYQUINOLINATO)- COPPER(II) [J].
BEVAN, JA ;
GRADDON, DP ;
MCCONNELL, JF .
NATURE, 1963, 199 (489) :373-&
[3]  
FALGUNI B, 1998, POLYHEDRON, V17, P2191
[4]   STRUCTURE OF (2,2'-BIPYRIDYL)SALICYLALDEHYDATOCOPPER(II) PERCHLORATE [J].
GARLAND, MT ;
LEMAROUILLE, JY ;
SPODINE, E .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :1518-1520
[5]   Aqua(4,7-diphenyl-1,10-phenanthroline)-(salicylaldehydato)copper(II) nitrate monohydrate [J].
Gasque, L ;
Moreno-Esparza, R ;
Ruiz-Ramírez, L ;
Medina-Dickinson, G .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 :1065-1067
[6]  
MING L, 1995, POLYHEDRON, V14, P639
[7]   Coordination geometries and cooperative ordering effects in copper(II) complexes with tridentate Schiff base dianions .5. Epr spectra of [N-salicylidene-(R,S)-alaninato]copper(II) complexes with derivatives of imidazole and pyrazole and structure of 1-methylimidazole[N-salicylidene-(R,S)-valinato]copper(II) [J].
Plesch, G ;
Friebel, C ;
Warda, SA ;
Sivy, J ;
Svajlenova, O .
TRANSITION METAL CHEMISTRY, 1997, 22 (05) :433-440
[8]  
REKI S, 1998, B CHEM SOC JPN, V71, P2365
[9]  
Sheldrick G.M., 1996, SADABS
[10]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122