High temperature SrCe0.9Eu0.1O3-δ proton conducting membrane reactor for H2 production using the water-gas shift reaction

被引：38

作者：

Li, Jianlin ^{[1
]}

Yoon, Heesung ^{[1
]}

Oh, Tak-Keun ^{[1
]}

Wachsman, Eric D. ^{[1
]}

机构：

[1] Univ Florida, Florida Inst Sustainable Energy, Gainesville, FL 32611 USA

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2009年 / 92卷 / 3-4期

关键词：

Water-gas shift reaction; Proton conducting membrane; Hydrogen; Permeation; SrCe0.9Eu0.1O3-delta; HYDROGEN SEPARATION MEMBRANES; ELECTRICAL-CONDUCTION; PERMEATION; CONVERSION; OXIDES; STEAM;

D O I：

10.1016/j.apcatb.2009.08.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The water-gas shift (WGS) reaction is used to shift the CO/H-2 ratio prior to Fischer-Tropsch synthesis and/or to increase H-2 yield. A WGS membrane reactor was developed using a mixed protonic-electronic conducting SrCe0.9Eu0.1O3-delta membrane coated on a Ni-SrCeO3-delta support. The membrane reactor overcomes the thermodynamic equilibrium limitations. A 46% increase in CO conversion and total H-2 yield was achieved at 900 degrees C under 3% CO and 6% H2O, resulting in a 92% single pass H-2 production yield and 32% single pass yield of pure permeated H-2. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：234 / 239

页数：6

共 50 条

[31] Modeling and simulation of H2S effect in high-temperature water-gas shift reaction using coal-derived syngas
Chein, R. Y.
Chen, Y. C.
Yu, C. T.
Chung, J. N.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (25) : 8051 - 8061
[32] Effect of Ce on the structural features and catalytic properties of La(0.9-x)CexFeO3 perovskite-like catalysts for the high temperature water-gas shift reaction
Sun, Y.
Hla, S. S.
Duffy, G. J.
Cousins, A. J.
French, D.
Morpeth, L. D.
Edwards, J. H.
Roberts, D. G.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) : 79 - 86
[33] Effect of Temperature and Steam-to-Carbon Monoxide (CO) Ratio on Hydrogen Production in Water-Gas Shift Reaction using Cu-ZnO-Al2O3 Catalyst
Desi, Sekar Kumala
Nursa'adah, Restu Siti
Anindita, Hana Nabila
Muharto, Bambang
Rahmawati, Nurdiah
Rini, Tyas Puspita
Rosyadi, Erlan
MAKARA JOURNAL OF SCIENCE, 2023, 27 (04) : 337 - 344
[34] Influence of CO2 and H2 on the low-temperature water-gas shift reaction on Au/CeO2 catalysts in idealized and realistic reformate
Denkwitz, Y.
Karpenko, A.
Plzak, V.
Leppelt, R.
Schumacher, B.
Behm, R. J.
JOURNAL OF CATALYSIS, 2007, 246 (01) : 74 - 90
[35] Numerical investigation and microkinetic modelling of high-temperature water-gas shift reaction for hydrogen production using iron-based catalysts
Dehimi, Leila
Benguerba, Yacine
Lemaoui, Tarek
Balsamo, Marco
Erto, Alessandro
JOURNAL OF CHEMICAL SCIENCES, 2024, 137 (01)
[36] Viability of Au/CeO2-ZnO/Al2O3 Catalysts for Pure Hydrogen Production by the Water-Gas Shift Reaction
Ramirez Reina, Tomas
Ivanova, Svetlana
Jose Delgado, Juan
Ivanov, Ivan
Idakiev, Vasko
Tabakova, Tatyana
Angel Centeno, Miguel
Antonio Odriozola, Jose
CHEMCATCHEM, 2014, 6 (05) : 1401 - 1409
[37] Low-temperature water-gas shift reaction over Mn-promoted Cu/Al2O3 catalysts
Yeragi, Dinesh C.
Pradhan, Narayan C.
Dalai, Ajay K.
CATALYSIS LETTERS, 2006, 112 (3-4) : 139 - 148
[38] Effect of H2S on the performance of La0.7Ce0.2FeO3 perovskite catalyst for high temperature water-gas shift reaction
Morpeth, L. D.
Sun, Y.
Hla, San Shwe
French, D.
Duffy, G. J.
Edwards, J. H.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (02) : 1475 - 1481
[39] H2 production through the water-gas shift reaction: An in situ time-resolved X-ray diffraction investigation of manganese OMS-2 catalyst
Sithambaram, Shanthakumar
Wen, Wen
Njagi, Eric
Shen, Xiong-Fei
Hanson, Jonathan C.
Suib, Steven L.
CATALYSIS TODAY, 2010, 156 (1-2) : 2 - 7
[40] A CeO2-La2O3-based Cu catalyst for the processing of coal-derived syngases via high-temperature water-gas shift reaction
Hla, San Shwe
Morpeth, L. D.
Sun, Y.
Duffy, G. J.
Ilyushechkin, A. Y.
Roberts, D. G.
Edwards, J. H.
FUEL, 2013, 114 : 178 - 186

← 1 2 3 4 5 →