The bonding of thiazoles to platinum(II) complexes. X-ray crystal structure of cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl-2]

被引：35

作者：

Cornia, A

Fabretti, AC

Bonivento, M

Cattalini, L

机构：

[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

[2] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1997年 / 255卷 / 02期

关键词：

platinum complexes; thiazole complexes; dimethyl sulfoxide complexes; crystal structures;

D O I：

10.1016/S0020-1693(96)05391-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of neutral cis- and trans-[Pt(dimethyl sulfoxide) (thiazole)Cl-2] have been determined by X-ray diffraction. The longer C4-C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.

引用

页码：405 / 409

页数：5

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