Completely Encapsulated Oligothiophenes: Synthesis, Properties, and Single-Molecule Conductance

被引：37

作者：

Le, Yutaka ^{[2
,3
]}

Endou, Masaru ^{[2
]}

Lee, See Kei ^{[1
]}

Yamada, Ryo ^{[1
]}

Tada, Hirokazu ^{[1
]}

Aso, Yoshio ^{[2
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Osaka Univ, ISIR, Osaka 5670047, Japan

[3] PREST JST, Kawaguchi, Saitama 3330012, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 50期

关键词：

conducting materials; conjugation; cyclic voltammetry; single-molecule studies; synthetic methods; EFFECTIVE CONJUGATION LENGTH; SPECTROSCOPIC PROPERTIES; ELECTRICAL CONDUCTANCE; WIRES; JUNCTIONS; ELECTRODES; UNITS;

D O I：

10.1002/anie.201104700

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proper shielding: Encapsulated oligothiophenes for the investigation of single-molecule conductance are described. UV/Vis/NIR measurements of the oxidized species show the absence of intermolecular interactions between the conjugated backbones. The conductance of a single-molecule junction was measured by modified STM techniques (see picture), and the decay constant β was determined to be 1.9 nm -1. SMU=source meter unit. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11980 / 11984

页数：5

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