Polymeric precursors from PET waste and their application in polyurethane coatings

被引:46
作者
Patel, MR [1 ]
Patel, JV
Sinha, VK
机构
[1] NV Patel Coll Pure & Appl Sci, Anand 388120, Gujarat, India
[2] Inst Sci & Technol Adv Studies & Res, Anand 388120, Gujarat, India
[3] VP & RPTP Sci Coll, Vallabh Vidyanagar 388120, Gujarat, India
关键词
PET; PET waste; glycol glycosides; depolymerisation; precursors; polyurethane;
D O I
10.1016/j.polymdegradstab.2005.02.017
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Starch derived polyhydric compounds were synthesised and utilised for depolymerisation of PET. Three different oligoesters were synthesised by reacting 5, 15 and 25 wt.% of PET. Depolymerised oligomers were esterified with coco fatty acid to give novel polymeric precursors - polyester polyols. Two-pack polyurethane coating systems were formulated using these polyols as base materials. Performance properties of these coating systems were evaluated. Depolymerisation of PET, polyol synthesis and polyurethane synthesis were characterised by FTIR spectroscopy. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:111 / 115
页数:5
相关论文
共 12 条
[1]   DEPOLYMERIZATION OF POLY(ETHYLENE-TEREPHTHALATE) RECYCLED FROM POST-CONSUMER SOFT-DRINK BOTTLES [J].
BALIGA, S ;
WONG, WT .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (06) :2071-2082
[2]  
COIN G, 1982, J APPL POLYM SCI, V26, P109
[3]   Polyurethane adhesive system from biomaterial-based polyol for bonding wood [J].
Desai, SD ;
Patel, JV ;
Sinha, VK .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2003, 23 (05) :393-399
[4]  
Guclu G, 1998, J APPL POLYM SCI, V69, P2311
[5]   PREPARATION OF OLIGOESTER DIOLS BY ALCOHOLYTIC DESTRUCTION OF POLY(ETHYLENE-TEREPHTHALATE) [J].
HALACHEVA, N ;
NOVAKOV, P .
POLYMER, 1995, 36 (04) :867-874
[6]  
Kizilcan N, 2000, J APPL POLYM SCI, V76, P648, DOI 10.1002/(SICI)1097-4628(20000502)76:5<648::AID-APP6>3.0.CO
[7]  
2-9
[8]   Depolyrnerization of poly(ethylene terephthalate) wastes using 1,4-butanediol and triethylene glycol [J].
Mansour, SH ;
Ikladious, NE .
POLYMER TESTING, 2002, 21 (05) :497-505
[9]   SEPARATION OF ISOMERIC GLYCOSIDES PRODUCED BY TRANSGLYCOSYLATION OF STARCH WITH ETHYLENE GLYCOL [J].
OTEY, FH ;
BENNETT, FL ;
ZAGOREN, BL ;
MEHLTRET.CL .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1965, 4 (04) :228-&
[10]  
SMOLUK GR, 1988, MOD PLAST, V65, P87