Synthesis of novel bifunctional hindered amine - UV absorber polymer stabilizers

被引：25

作者：

Bojinov, VB ^{[1
]}

机构：

[1] Univ Chem Technol & Met, Dept Organ Synth, BU-1756 Sofia, Bulgaria

来源：

POLYMER DEGRADATION AND STABILITY | 2006年 / 91卷 / 01期

关键词：

bifunctional polymerisable stabilizers; 2,2,6,6-tetramethylpiperidines; 2-(2-hydroxyphenyl)-benzotriazoles; phase transfer catalysis; copolymerisation; photo-stability;

D O I：

10.1016/j.polymdegradstab.2005.04.019

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of new stabilizer compounds (a combination between 2,2,6,6-tetramethylpiperidine and 2-hydroxyphenylbenzotriazole in one molecule) is reported. Four polymerisable combined stabilizers as well as two unsaturated triazinyl-2,2,6,6-tetramethylpiperidines and two unsaturated triazinyl-2-hydroxyphenylbenzotriazoles as individual stabilizers were synthesized. Their copolymers and terpolyrners of the individual stabilizers with acrylonitrile were obtained. Chemical bonding of the stabilizers in the polymer was confirmed spectrophotometrically. The influence of these additives on the photo-stability of the copolymers was studied. The participation of the combined stabilizers in the polymerisation did not significantly affect the molecular weight and polydispersity of the copolymers. A significant stabilizing effect against photodegradation was found. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：128 / 135

页数：8

共 24 条

[1] RECENT ADVANCES IN THE PHOTOOXIDATION AND STABILIZATION OF POLYMERS [J].

ALLEN, NS .

CHEMICAL SOCIETY REVIEWS, 1986, 15 (03) :373-404

[2] Synthesis and properties of new adducts of 2,2,6,6-tetramethylpiperidine and 2-hydroxyphenylbenzotriazole as polymer photo stabilizers [J].

Bojinov, V ;

Grabchev, I .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 150 (1-3) :223-231

[3] Synthesis and application of new combined 2,2,6,6-tetramethylpiperidine-2-hydroxybenzophenone 1,3,5-triazine derivatives as photostabilizers for polymer materials [J].

Bojinov, V ;

Grabchev, I .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 146 (03) :199-205

[4] Synthesis and properties of adducts of a hindered amine and 2-hydroxyphenylbenzotriazole as novel polymer stabilizers [J].

Bojinov, V .

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2002, 1 (05) :340-346

[5]

Bojinov V, 1998, ANGEW MAKROMOL CHEM, V260, P17

[6] On the possibility of "one-step" colouration and stabilization of polystyrene [J].

Bojinov, V ;

Konstantinova, T .

POLYMER DEGRADATION AND STABILITY, 2000, 68 (02) :295-298

[7] Synthesis of new combined 2,2,6,6-tetramethylpiperidine-2-hydroxyphenylbenzotriazole 1,3,5-triazine derivatives as stabilizers for polymers [J].

Bojinov, VB ;

Grabchev, I .

POLYMER DEGRADATION AND STABILITY, 2001, 74 (03) :543-550

[8] 2(2-hydroxyphenyl)2H-benzotriazole ultraviolet stabilizers [J].

Crawford, JC .

PROGRESS IN POLYMER SCIENCE, 1999, 24 (01) :7-43

[9] PHOTOCHEMISTRY OF KETONE POLYMERS .9. TRIPLET ENERGY-TRANSFER IN POLYVINYL KETONES) [J].

DAN, E ;

SOMERSAL.AC ;

GUILLET, JE .

MACROMOLECULES, 1973, 6 (02) :228-230

[10] Aspects of the impact of stabilizer mass on performance in polymers - 3. Performance of HALS in polyethylene [J].

Gugumus, F .

POLYMER DEGRADATION AND STABILITY, 2000, 69 (01) :93-104

← 1 2 3 →