Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

被引：8

作者：

Stanlake, Louisa J. E. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 22期

基金：

加拿大自然科学与工程研究理事会;

关键词：

COMPLEXES; CHEMISTRY; REACTIVITY; LIGANDS;

D O I：

10.1039/c1dt10452g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ZnMe complexes of bis-ferrocenyl-beta-diketiminate ligands are prepared and the reactions with [Ph3C][B(C6F5)(4)] are found to yield the salts [H(Ph3C) C( MeC(N(C5H4)FeCp)(2)ZnMe] [B(C6F5)(4)] and [CH2 = C(MeC(N(C5H4)FeCp)(2)ZnMe][B(C6F5)(4)], derived from electrophilic substitution and hydride abstraction.

引用

页码：5836 / 5840

页数：5

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