Hydrodechlorination of 1,2,4-trichlorbenzene over supported ruthenium catalysts on various supports

被引：24
作者：
Srikanth, Chakravartula S. [1 ]
Kumar, Vanama Pavan [1 ]
Viswanadham, Balaga [1 ]
Chary, Komandur V. R. [1 ]
机构：
[1] Indian Inst Chem Technol, Catalysis Div, Hyderabad 500007, Andhra Pradesh, India
来源：
CATALYSIS COMMUNICATIONS | 2011年 / 13卷 / 01期
关键词：
Ru catalysts; Dispersion; Hydrodechlorination; 1,2,4-trichlorobenzene; PARASUBSTITUTED CHLOROBENZENES; REACTIVITY;
D O I：
10.1016/j.catcom.2011.06.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrodechlorination of 1,2,4-trichlorbenzene was carried out over ruthenium catalysts supported on gamma-Al2O3, CeO2, ZrO2, SiO2, SBA-15 and activated carbon. In the hydrodechlorination of 1,2,4-trichlorobenzene, higher catalytic activities and longer catalyst life was achieved for Ru catalysts supported on carbon compared to Ru catalysts supported on other supports. The higher catalytic activity exhibited by carbon supported ruthenium catalysts was attributed due to high dispersion of Ru, metal area and smaller crystallite size owing to strong chemisorption of 1,2,4-trichlorobenzene leading to complete hydrodechlorination. (C) 2011 Elsevier B.V. All rights reserved.
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收藏
页码：69 / 72
页数：4
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